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Title compound\n                    <jats:bold>2<\/jats:bold>\n                    features an extraordinarily high N\n                    <jats:sub>2<\/jats:sub>\n                    stretching frequency at 2313\/2314\u2005cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    (IR\/Raman) and was characterized by single\u2010crystal and powder X\u2010ray diffractometry. Quantum chemical charge displacement analysis based on natural orbitals of chemical valence (CD\u2010NOCV) indicates that the copper\u2010dinitrogen interaction is still governed by weak \u03c0\n                    <jats:italic>\u2010<\/jats:italic>\n                    backdonation, but is significantly reduced compared to all literature\u2010known transition metal dinitrogen complexes.\n                  <\/jats:p>","DOI":"10.1002\/anie.202405330","type":"journal-article","created":{"date-parts":[[2024,6,11]],"date-time":"2024-06-11T02:00:51Z","timestamp":1718071251000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2810-3530","authenticated-orcid":false,"given":"Julie","family":"Willrett","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF) Albert-Ludwigs-Universit\u00e4t Freiburg  Albertstr. 21 79104 Freiburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1670-4099","authenticated-orcid":false,"given":"Manuel","family":"Schmitt","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF) Albert-Ludwigs-Universit\u00e4t Freiburg  Albertstr. 21 79104 Freiburg Germany"},{"name":"Anorganisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vadim","family":"Zhuravlev","sequence":"additional","affiliation":[{"name":"Centre of New Technologies University of Warsaw  Banacha 2c 02097 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0424-2261","authenticated-orcid":false,"given":"Malte","family":"Sellin","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF) Albert-Ludwigs-Universit\u00e4t Freiburg  Albertstr. 21 79104 Freiburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6681-6721","authenticated-orcid":false,"given":"Przemys\u0142aw J.","family":"Malinowski","sequence":"additional","affiliation":[{"name":"Centre of New Technologies University of Warsaw  Banacha 2c 02097 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7182-4387","authenticated-orcid":false,"given":"Ingo","family":"Krossing","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF) Albert-Ludwigs-Universit\u00e4t Freiburg  Albertstr. 21 79104 Freiburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,14]]},"reference":[{"key":"e_1_2_3_1_1","first-page":"621","author":"Allen A. 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