{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T02:03:59Z","timestamp":1790906639899,"version":"4.1.0"},"reference-count":87,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2024,4,29]],"date-time":"2024-04-29T00:00:00Z","timestamp":1714348800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,6,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Through a coordination\u2010driven self\u2010assembly method, four \n metalla\u2010links and one tetranuclear monocycle were constructed with high selectivity and yield by adjusting the substituent species of the building blocks, as evidenced using X\u2010ray crystallographic analysis, electrospray ionization\u2010time\u2010of\u2010flight\/mass spectrometry (ESI\u2010TOF\/MS), elemental analysis and detailed solution\u2010state nuclear magnetic resonance (NMR) spectroscopy. Based on X\u2010ray crystallographic analysis and independent gradient model analysis, a significant factor leading to the formation of \n metalla\u2010links was the introduction of F, Cl, Br and I atoms, which generated additional weak C\u2212H\u22c5\u22c5\u22c5X (X=F, Cl, Br and I) interactions. Furthermore, the dynamic conversion of \n metalla\u2010links to monocyclic rings in methanol solution was systematically investigated using quantitative <jats:sup>1<\/jats:sup>H NMR techniques.<\/jats:p>","DOI":"10.1002\/anie.202405399","type":"journal-article","created":{"date-parts":[[2024,4,4]],"date-time":"2024-04-04T01:59:50Z","timestamp":1712195990000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Efficient and Selective Construction of 4<sub>1<\/sub><sup>2<\/sup> Metalla\u2010links Using Weak C\u2212H\u22c5\u22c5\u22c5Halogen Interactions"],"prefix":"10.1002","volume":"63","author":[{"given":"Hai\u2010Ning","family":"Zhang","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers Department of Chemistry Fudan University  2005 Songhu Rd 200438 Shanghai P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xi","family":"Huang","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers Department of Chemistry Fudan University  2005 Songhu Rd 200438 Shanghai P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7149-5413","authenticated-orcid":false,"given":"Guo\u2010Xin","family":"Jin","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers Department of Chemistry Fudan University  2005 Songhu Rd 200438 Shanghai P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,4,29]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b008033k"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2004.05.062"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00516J"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503132"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35239G"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7MD00381A"},{"key":"e_1_2_8_8_1","unstructured":"\u00a0"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00212a065"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja960307r"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0155-z"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012315"},{"key":"e_1_2_8_13_1","unstructured":"\u00a0"},{"key":"e_1_2_8_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00039a047"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/38985"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja012058z"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610901"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00155C"},{"key":"e_1_2_8_19_1","unstructured":"\u00a0"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar040153h"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar980101q"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar900077c"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar500335a"},{"key":"e_1_2_8_24_1","unstructured":"\u00a0"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/b901649j"},{"key":"e_1_2_8_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/b922293f"},{"key":"e_1_2_8_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200077m"},{"key":"e_1_2_8_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35162e"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35123D"},{"key":"e_1_2_8_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5005666"},{"key":"e_1_2_8_31_1","unstructured":"\u00a0"},{"key":"e_1_2_8_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411619"},{"key":"e_1_2_8_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702531"},{"key":"e_1_2_8_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00321"},{"key":"e_1_2_8_35_2","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.021.202100975"},{"key":"e_1_2_8_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00323F"},{"key":"e_1_2_8_37_1","unstructured":"\u00a0"},{"key":"e_1_2_8_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c08094"},{"key":"e_1_2_8_39_2","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-022-00094-5"},{"key":"e_1_2_8_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13416"},{"key":"e_1_2_8_41_2","volume":"62","author":"Baby Sainaba A.","year":"2023","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_42_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-023-1675-0"},{"key":"e_1_2_8_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202308288"},{"key":"e_1_2_8_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202300359"},{"key":"e_1_2_8_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312323"},{"key":"e_1_2_8_46_1","unstructured":"\u00a0"},{"key":"e_1_2_8_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913142"},{"key":"e_1_2_8_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12064"},{"key":"e_1_2_8_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03208"},{"key":"e_1_2_8_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303714"},{"key":"e_1_2_8_51_1","unstructured":"\u00a0"},{"key":"e_1_2_8_52_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2017.06.006"},{"key":"e_1_2_8_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900556"},{"key":"e_1_2_8_54_1","unstructured":"\u00a0"},{"key":"e_1_2_8_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_2_8_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP02110K"},{"key":"e_1_2_8_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.26812"},{"key":"e_1_2_8_58_2","author":"Lu T.","year":"2022","journal-title":"ChemRxiv."},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"},{"key":"e_1_2_8_60_1","unstructured":"\u00a0"},{"key":"e_1_2_8_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar0100475"},{"key":"e_1_2_8_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/j150653a013"},{"key":"e_1_2_8_63_1","unstructured":"\u00a0"},{"key":"e_1_2_8_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703168"},{"key":"e_1_2_8_65_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4OB01373E"},{"key":"e_1_2_8_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b01326"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.2307\/1968399"},{"key":"e_1_2_8_68_1","first-page":"1552","volume":"45","author":"Zefirov Y. V.","year":"2000","journal-title":"Russ. J. Inorg. Chem."},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.5b00415"},{"key":"e_1_2_8_70_1","unstructured":"\u00a0"},{"key":"e_1_2_8_71_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U"},{"key":"e_1_2_8_72_2","doi-asserted-by":"publisher","DOI":"10.3390\/cryst11040325"},{"key":"e_1_2_8_73_1","unstructured":"Deposition Numbers2314913 (for1) 2314914 (for3) 2314915 (for4) 2314916 (for5)contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_8_74_1","unstructured":"\u00a0"},{"key":"e_1_2_8_75_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-017-01903-0"},{"key":"e_1_2_8_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201805383"},{"key":"e_1_2_8_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/om100106e"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889808042726"},{"key":"e_1_2_8_79_1","unstructured":"\u00a0"},{"key":"e_1_2_8_80_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767390000277"},{"key":"e_1_2_8_81_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_8_82_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_83_1","unstructured":"\u00a0"},{"key":"e_1_2_8_84_2","doi-asserted-by":"publisher","DOI":"10.1021\/ed047p261"},{"key":"e_1_2_8_85_2","doi-asserted-by":"publisher","DOI":"10.1039\/B615067P"},{"key":"e_1_2_8_86_2","doi-asserted-by":"publisher","DOI":"10.1021\/j150665a063"},{"key":"e_1_2_8_87_1","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2012.70"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202405399","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,11,28]],"date-time":"2024-11-28T06:49:17Z","timestamp":1732776557000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202405399"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,4,29]]},"references-count":87,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2024,6,3]]}},"alternative-id":["10.1002\/anie.202405399"],"URL":"https:\/\/doi.org\/10.1002\/anie.202405399","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,4,29]]},"assertion":[{"value":"2024-03-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-04-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202405399"}}