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While the Cu(110) and full CuO films are inert, the interface between bare Cu(110) and the CuO film is observed to react instantly with CO<jats:sub>2<\/jats:sub> at a 10\u2005mbar pressure. The reaction is observed to proceed from the interfacial sites of CuO\/Cu(110). During reaction with CO<jats:sub>2<\/jats:sub>, the CuO\/Cu(110) interface releases Cu adatoms which combine with CO<jats:sub>3<\/jats:sub> to produce a variety of added Cu\u2212CO<jats:sub>3<\/jats:sub> structures, whose stability depends on the gas pressure of CO<jats:sub>2<\/jats:sub>. A main implication for the reactivity of Cu(110) is that Cu adatoms and highly undercoordinated CuO segments are created on the Cu(110) surface through the interaction with CO<jats:sub>2<\/jats:sub>, which may act as reaction\u2010induced active sites. In the case of CO<jats:sub>2<\/jats:sub> hydrogenation to methanol, our theoretical assessment of such sites indicates that their presence may significantly promote CH<jats:sub>3<\/jats:sub>OH formation. Our study thus implies that the CuO\/Cu(110) interfacial system is highly dynamic in the presence of CO<jats:sub>2<\/jats:sub>, and it suggests a possible strong importance of reaction\u2010induced Cu and CuO sites for the surface chemistry of Cu(110) in CO<jats:sub>2<\/jats:sub>\u2010related catalysis.<\/jats:p>","DOI":"10.1002\/anie.202405554","type":"journal-article","created":{"date-parts":[[2024,6,4]],"date-time":"2024-06-04T08:16:50Z","timestamp":1717489010000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Role of Cu Oxide and Cu Adatoms in the Reactivity of CO<sub>2<\/sub> on Cu(110)"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2191-9780","authenticated-orcid":false,"given":"Sigmund","family":"Jensen","sequence":"first","affiliation":[{"name":"Interdisciplinary Nanoscience Center (iNANO) Aarhus University  8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0729-9389","authenticated-orcid":false,"given":"Raffaele","family":"Cheula","sequence":"additional","affiliation":[{"name":"Center for Interstellar Catalysis, Department of Physics and Astronomy Aarhus University  8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-1611-7541","authenticated-orcid":false,"given":"Martin","family":"Hedevang","sequence":"additional","affiliation":[{"name":"Interdisciplinary Nanoscience Center (iNANO) Aarhus University  8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9943-1534","authenticated-orcid":false,"given":"Mie","family":"Andersen","sequence":"additional","affiliation":[{"name":"Interdisciplinary Nanoscience Center (iNANO) Aarhus University  8000 Aarhus C Denmark"},{"name":"Center for Interstellar Catalysis, Department of Physics and Astronomy Aarhus University  8000 Aarhus C Denmark"},{"name":"Aarhus Institute of Advanced Studies Aarhus University  8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4953-652X","authenticated-orcid":false,"given":"Jeppe V.","family":"Lauritsen","sequence":"additional","affiliation":[{"name":"Interdisciplinary Nanoscience Center (iNANO) Aarhus University  8000 Aarhus C Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,7,16]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0266-y"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07882-8"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36530-z"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00940-4"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-019-0282-1"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b02083"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfrep.2016.09.001"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY00922B"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c01005"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00583D"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111021"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b01755"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2012649118"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2021.05.016"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(91)85070-I"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-5729(96)00007-6"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2007.11.030"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1116\/1.578101"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2005.11.013"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/a904169i"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(92)90460-N"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1098\/rsta.2004.1544"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp049469x"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04039"},{"key":"e_1_2_8_26_1","first-page":"1","volume":"14","author":"Kim J.","year":"2023","journal-title":"Nat. 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