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However, the expansion of radical scope and enantiocontrol remain two major challenges. Herein, we describe an unprecedented photoinduced copper\u2010catalyzed highly enantioselective three\u2010component radical 1,2\u2010azidooxygenation of 1,3\u2010dienes with readily available azidobenziodazolone reagent and carboxylic acids. This mild protocol exhibits a broad substrate scope, high functional group tolerance, and exceptional control over chemo\u2010, regio\u2010 and enantioselectivity, providing practical access to diverse valuable azidated chiral allylic esters. 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