{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T01:57:56Z","timestamp":1791856676536,"version":"4.3.4"},"reference-count":43,"publisher":"Wiley","issue":"31","license":[{"start":{"date-parts":[[2024,6,27]],"date-time":"2024-06-27T00:00:00Z","timestamp":1719446400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22125801"],"award-info":[{"award-number":["22125801"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,7,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Organic solvent nanofiltration (OSN) plays important roles in pharmaceutical ingredients purification and solvent recovery. However, the low organic solvent permeance under cross\u2010flow operation of OSN membrane hampers their industrial applications. Herein, we report the construction of coffee\u2010ring structured membrane featuring high OSN permeance. A water\u2010insoluble crystal monomer that dissolved in EtOH\/H\n                    <jats:sub>2<\/jats:sub>\n                    O mixed solvent was designed to react with trimesoyl chloride via interfacial polymerization. Owing to the diffusion of EtOH to n\u2010hexane, coffee\u2010ring nanostructure on the support membrane appeared, which served as the template for construction of coffee\u2010ring structured membrane. The optimal nanostructured membrane demonstrated 2.6\u2010fold enhancement in the effective surface area with reduced membrane thickness. Resultantly, the membrane afforded a 2.7\u2010fold enhancement in organic solvent permeance, e.g., ~13\u2005LMH\/bar for MeOH, without sacrificing the rejection ability. Moreover, due to the rigid monomer structure, the fabricated membrane shows distinctive running stability in active pharmaceutical ingredients purification and the ability for concentration of medicines.\n                  <\/jats:p>","DOI":"10.1002\/anie.202405891","type":"journal-article","created":{"date-parts":[[2024,5,20]],"date-time":"2024-05-20T22:26:10Z","timestamp":1716243970000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["Fabrication of Coffee\u2010Ring Nanostructured Membranes for Organic Solvent Nanofiltration"],"prefix":"10.1002","volume":"63","author":[{"given":"Cheng\u2010Gang","family":"Jin","sequence":"first","affiliation":[{"name":"Beijing Key Laboratory for Green Catalysis and Separation Department of Chemical Engineering College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Hai","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Green Catalysis and Separation Department of Chemical Engineering College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Na","family":"Tian","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Green Catalysis and Separation Department of Chemical Engineering College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Wu","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Green Catalysis and Separation Department of Chemical Engineering College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming\u2010Jie","family":"Yin","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Green Catalysis and Separation Department of Chemical Engineering College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6574-9368","authenticated-orcid":false,"given":"Quan\u2010Fu","family":"An","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Green Catalysis and Separation Department of Chemical Engineering College of Materials Science and Engineering Beijing University of Technology  Beijing 100124 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,27]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.202100575"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1080\/15422119.2014.918884"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500006j"},{"key":"e_1_2_7_5_1","unstructured":"Precedence Research \u201cGlobal Industry Analysis Size Share Growth Trends Regional Outlook and Forecast 2023\u20132032\u201d can be found underhttps:\/\/www.precedenceresearch.com\/solvents-market(accessed 15\u2005October 2023)."},{"key":"e_1_2_7_6_1","unstructured":"\u00a0"},{"key":"e_1_2_7_7_2","unstructured":"O.\u2005R.\u2005N. 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