{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T03:08:30Z","timestamp":1791342510499,"version":"4.3.1"},"reference-count":55,"publisher":"Wiley","issue":"46","license":[{"start":{"date-parts":[[2024,8,25]],"date-time":"2024-08-25T00:00:00Z","timestamp":1724544000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52202228"],"award-info":[{"award-number":["52202228"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,11,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Sodium\u2010ion batteries (SIBs) have garnered significant interest as one of the most promising energy suppliers for power grid energy storage. However, the poor electrode\/electrolyte interfacial stability leads to continual electrolyte decomposition and transition metal dissolution, resulting in rapid performance degradation of SIBs. In this work, we propose a strategy integrating multiple functional bonds to regulate electrode\/electrolyte interphase by triple\u2010coupling of succinonitrile (SN), sodium hexafluorophosphate (NaPF\n                    <jats:sub>6<\/jats:sub>\n                    ) and fluorinated ethylene carbonate (FEC). Theoretical calculation and experiment results show that the solvation structure of Na\n                    <jats:sup>+<\/jats:sup>\n                    and ClO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    is effectively reconfigured by the solvated FEC, SN and PF\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    in PC\u2010based carbonate electrolyte. The newly developed electrolyte demonstrates increased Na\n                    <jats:sup>+<\/jats:sup>\n                    \u2010FEC coordination, weakened interaction of Na\n                    <jats:sup>+<\/jats:sup>\n                    \u2010PC and participation of SN and PF\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    anions in solvation, resulting in the formation of a conformal interfacial layer comprising of sodium oxynitrides (NaN\n                    <jats:sub>x<\/jats:sub>\n                    O\n                    <jats:sub>y<\/jats:sub>\n                    ), sodium fluoride (NaF) and phosphorus oxide compounds (NaP\n                    <jats:sub>x<\/jats:sub>\n                    O\n                    <jats:sub>y<\/jats:sub>\n                    ). Consequently, a 3\u2005Ah pouch full cell of hard carbon\/\/NaNi\n                    <jats:sub>1\/3<\/jats:sub>\n                    Fe\n                    <jats:sub>1\/3<\/jats:sub>\n                    Mn\n                    <jats:sub>1\/3<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    exhibits an excellent capacity retention of 90.4\u2009% after 1000\u2005cycles. Detailed postmortem analysis of interface chemistry is further illustrated by multiple characterization methods. This study provides a new avenue for developing electrolyte formulations with multiple functional bonds integrated interphases to significantly improve the long\u2010term cycling stability of SIBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202406277","type":"journal-article","created":{"date-parts":[[2024,6,28]],"date-time":"2024-06-28T13:50:48Z","timestamp":1719582648000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":42,"title":["Multiple Functional Bonds Integrated Interphases for Long Cycle Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"63","author":[{"given":"Yongsheng","family":"Huang","sequence":"first","affiliation":[{"name":"Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and Engineering Hebei University of Technology  Tianjin 300130 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingqing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and Engineering Hebei University of Technology  Tianjin 300130 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Guang","family":"Sun","sequence":"additional","affiliation":[{"name":"Chemical Sciences Division Oak Ridge National Laboratory  Oak Ridge TN 37831 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5546-0926","authenticated-orcid":false,"given":"Kai","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weili","family":"Sun","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and Engineering Hebei University of Technology  Tianjin 300130 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyu","family":"Zhi","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and Engineering Hebei University of Technology  Tianjin 300130 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yayu","family":"Guo","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shijian","family":"Zheng","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and Engineering Hebei University of Technology  Tianjin 300130 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sheng","family":"Dai","sequence":"additional","affiliation":[{"name":"Chemical Sciences Division Oak Ridge National Laboratory  Oak Ridge TN 37831 USA"},{"name":"Department of Chemistry University of Tennessee  Knoxville TN 37996 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01215-w"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202001274"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/inf2.12475"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201701428"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202300780"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA10329F"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-023-01396-1"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202204407"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.145991"},{"key":"e_1_2_7_10_1","author":"Liu Y.","year":"2024","journal-title":"Adv. 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