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While the dimensionally stable anode (DSA) displays commendable catalytic activity and longevity, they rely on precious metals and exhibit a non\u2010negligible side reaction in sodium hypochlorite (NaClO) production, underscoring the appeal of metal\u2010free alternatives. However, the molecules and systems currently available are characterized by intricate complexity and are not amenable to large\u2010scale production. Herein, we have successfully developed an economical and highly efficient molecular catalyst, demonstrating superior performance compared with the former organic molecules in the chloride ion oxidation process (COP) for the production of both chlorine gas (Cl\n                    <jats:sub>2<\/jats:sub>\n                    ) and NaClO. The molecule of 2N only needs 92\u2005mV to reach a current density of 1000\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , with a small cost of only 0.002\u2005$\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Furthermore, we propose a novel mechanism underpinned by non\u2010covalent interactions, serving as the foundation for an innovative approach to the design of efficient anodes for the COP.\n                  <\/jats:p>","DOI":"10.1002\/anie.202406883","type":"journal-article","created":{"date-parts":[[2024,5,24]],"date-time":"2024-05-24T03:09:55Z","timestamp":1716520195000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":53,"title":["A Simple Organo\u2010Electrocatalysis System for the Chlor\u2010Related Industry"],"prefix":"10.1002","volume":"63","author":[{"given":"Jiarui","family":"Yang","sequence":"first","affiliation":[{"name":"Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenxi","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0074-7633","authenticated-orcid":false,"given":"Dingsheng","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,7,2]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"Chlorine Industry Review 2022\u20132023 Euro Chlor https:\/\/www.chlorineindustryreview.com\/wp-content\/uploads\/2023\/10\/Chlor-Alkali-Industry-Review-CORRECTED-2023\u201310-06.pdf2024."},{"key":"e_1_2_7_2_1","doi-asserted-by":"crossref","unstructured":"J. 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