{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T20:02:47Z","timestamp":1791835367009,"version":"4.3.4"},"reference-count":79,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2024,9,6]],"date-time":"2024-09-06T00:00:00Z","timestamp":1725580800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,9,6]],"date-time":"2024-09-06T00:00:00Z","timestamp":1725580800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFB4001200"],"award-info":[{"award-number":["2021YFB4001200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22272121"],"award-info":[{"award-number":["22272121"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21972107"],"award-info":[{"award-number":["21972107"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,10,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Transition metal\/p\u2010block compounds are regarded as the most essential materials for electrochemical energy converting systems involving various electrocatalysis. Understanding the role of p\u2010block element on the interaction of key intermediates and interfacial water molecule orientation at the polarized catalyst\u2010electrolyte interface during the electrocatalysis is important for rational designing advanced p\u2010block modified metal electrocatalysts. Herein, taking a sequence of ruthenium phosphides (including Ru\n                    <jats:sub>2<\/jats:sub>\n                    P, RuP and RuP\n                    <jats:sub>2<\/jats:sub>\n                    ) as model catalysts, we establish a volcanic\u2010relation between P\u2010proportion and alkaline hydrogen oxidation reaction (HOR) activity. The dominant role of P for regulating hydroxyl binding energy is validated by active sites poisoning experiments, pH\u2010dependent infection\u2010point behavior, in situ surface enhanced infrared absorption spectroscopy, and density functional theory calculations, in which P could tailor the d\u2010band structure of Ru, optimize the hydroxyl adsorption sites across the Ru\u2212P moieties, thereby leading to improved proportion of strongly hydrogen\u2010bonded water and facilitated proton\u2010coupled electron transfer process, which are responsible for the enhanced alkaline HOR performance.\n                  <\/jats:p>","DOI":"10.1002\/anie.202406888","type":"journal-article","created":{"date-parts":[[2024,7,15]],"date-time":"2024-07-15T08:38:24Z","timestamp":1721032704000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["The Role of Phosphorus on Alkaline Hydrogen Oxidation Electrocatalysis for Ruthenium Phosphides"],"prefix":"10.1002","volume":"63","author":[{"given":"Yiming","family":"Jin","sequence":"first","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan, Hubei 430072 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinran","family":"Fan","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan, Hubei 430072 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjing","family":"Cheng","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan, Hubei 430072 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuheng","family":"Zhou","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan, Hubei 430072 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Xiao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan, Hubei 430072 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7807-1373","authenticated-orcid":false,"given":"Wei","family":"Luo","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan, Hubei 430072 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,9,6]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00445G"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00827-4"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aas9793"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00862-8"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202206588"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03135"},{"key":"e_1_2_7_9_1","unstructured":"\u00a0"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915663"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-023-01142-1"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201902751"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-06728-7"},{"key":"e_1_2_7_15_1","unstructured":"\u00a0"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29929-7"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01649"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315752"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202215585"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201801891"},{"key":"e_1_2_7_22_1","unstructured":"\u00a0"},{"key":"e_1_2_7_23_2","author":"Yang C.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37360-9"},{"key":"e_1_2_7_25_2","author":"Zhang W.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309732"},{"key":"e_1_2_7_27_1","unstructured":"\u00a0"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00878-7"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01047-7"},{"key":"e_1_2_7_30_1","unstructured":"\u00a0"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.1501602"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6848"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE01754J"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015571"},{"key":"e_1_2_7_35_1","unstructured":"\u00a0"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1211934"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-00710-8"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abm3779"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45369-x"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00846-8"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c09128"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01302-y"},{"key":"e_1_2_7_43_1","unstructured":"\u00a0"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202301469"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE02577A"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00323B"},{"key":"e_1_2_7_47_1","unstructured":"\u00a0"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130491"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c05691"},{"key":"e_1_2_7_50_1","unstructured":"\u00a0"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA10346E"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201800047"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120917"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c05691"},{"key":"e_1_2_7_55_1","unstructured":"\u00a0"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311937"},{"key":"e_1_2_7_57_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19413-5"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217275"},{"key":"e_1_2_7_59_1","unstructured":"\u00a0"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11734"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105049"},{"key":"e_1_2_7_62_1","unstructured":"\u00a0"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01164"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-023-1709-0"},{"key":"e_1_2_7_65_1","unstructured":"\u00a0"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-22996-2"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02487"},{"key":"e_1_2_7_68_1","unstructured":"\u00a0"},{"key":"e_1_2_7_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp953636z"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12101"},{"key":"e_1_2_7_71_1","unstructured":"\u00a0"},{"key":"e_1_2_7_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.1c00281"},{"key":"e_1_2_7_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz100424e"},{"key":"e_1_2_7_74_1","unstructured":"\u00a0"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1006\/jcat.2000.3136"},{"key":"e_1_2_7_76_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31660-2"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01017-z"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207114"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01448"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202406888","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202406888","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202406888","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T16:52:59Z","timestamp":1784307179000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202406888"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,9,6]]},"references-count":79,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2024,10,7]]}},"alternative-id":["10.1002\/anie.202406888"],"URL":"https:\/\/doi.org\/10.1002\/anie.202406888","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,9,6]]},"assertion":[{"value":"2024-04-10","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-09-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202406888"}}