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Here, we report the first examples of intermolecular oxidative addition of E\u2212H (E=C, N) bonds to uranium(II) centers. The transient U(II) species was formed\n                    <jats:italic>in\u2010situ<\/jats:italic>\n                    by reducing a heterometallic cluster featuring U(IV)\u2010Pd(0) bonds with potassium\u2010graphite (KC\n                    <jats:sub>8<\/jats:sub>\n                    ). Oxidative addition of C\u2212H or N\u2212H bonds to the U(II) centers was observed when this transient U(II) species was treated with benzene, carbazole or 1\u2010adamantylamine, respectively. The U(II) centers could also react with tetracene, biphenylene or N\n                    <jats:sub>2<\/jats:sub>\n                    O, leading to the formation of arene reduced U(IV) products and uranyl(VI) species via two\u2010 or four\u2010electron processes. This study demonstrates that the intermolecular two\u2010electron oxidative addition reactions are viable for actinide elements.\n                  <\/jats:p>","DOI":"10.1002\/anie.202407339","type":"journal-article","created":{"date-parts":[[2024,5,7]],"date-time":"2024-05-07T21:59:59Z","timestamp":1715119199000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Oxidative Addition of E\u2212H (E=C, N) Bonds to Transient Uranium(II) Centers"],"prefix":"10.1002","volume":"63","author":[{"given":"Wei","family":"Fang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yafei","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination 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