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Here, we introduce the double\u2010ended amide molecule into perovskite precursor solution to modulate crystallization process and passivate defects. By regulating the intermediate bridging skeletons with alkyl, alkenyl and benzene groups, the results show the passivation strength highly depends on the spin\u2010state electronic structure that serves as an intrinsic descriptor to determine the intramolecular charge distribution by controlling orbital electron transfer from the donor segment to acceptor segment. Upon careful optimization, the benzene\u2010bridged amide molecule demonstrates superior efficacy on improving perovskite film quality. As a physical proof\u2010of\u2010concept, the carbon\u2010based, all\u2010inorganic CsPbI\n                    <jats:sub>2<\/jats:sub>\n                    Br solar cell delivers a significantly increased efficiency of 15.51\u2009% with a remarkably improved stability. Based on the same principle, a champion efficiency of 24.20\u2009% is further obtained on the inverted (Cs\n                    <jats:sub>0.05<\/jats:sub>\n                    MA\n                    <jats:sub>0.05<\/jats:sub>\n                    FA\n                    <jats:sub>0.9<\/jats:sub>\n                    )Pb(I\n                    <jats:sub>0.93<\/jats:sub>\n                    Br\n                    <jats:sub>0.07<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    solar cell. These findings provide new fundamental insights into the influence of spin\u2010state modulation on effective perovskite solar cells.\n                  <\/jats:p>","DOI":"10.1002\/anie.202407383","type":"journal-article","created":{"date-parts":[[2024,5,16]],"date-time":"2024-05-16T01:44:20Z","timestamp":1715823860000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["Influence of Donor Skeleton on Intramolecular Electron Transfer Amount for Efficient Perovskite Solar Cells"],"prefix":"10.1002","volume":"63","author":[{"given":"Shengwei","family":"Geng","sequence":"first","affiliation":[{"name":"Institute of Carbon Neutrality College of Chemical and Biological Engineering Shandong University of Science and Technology  Qingdao 266590 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jialong","family":"Duan","sequence":"additional","affiliation":[{"name":"Institute of Carbon Neutrality College 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