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Herein, we report a dual\u2010site strategy to boost the catalytic efficiency of CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010methanol conversion. A new descriptor,\n                    <jats:italic>\u03c4<\/jats:italic>\n                    , was initially established for screening the promising candidates with low\u2010temperature activation capability of CO\n                    <jats:sub>2<\/jats:sub>\n                    , and sequentially a high\u2010performance catalyst was fabricated centred with oxophilic Mo single atoms, who was further decorated with Pt nanoparticles. In CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation, the obtained dual\u2010site catalysts possess a remarkably\u2010improved methanol generation rate (0.27\u2005mmol\u2009g\n                    <jats:sub>cat.<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). For comparison, the singe\u2010site Mo and Pt\u2010based catalysts can only produce ethanol and formate acid at a relatively low reaction rate (0.11\u2005mmol\u2009g\n                    <jats:sub>cat.<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    for ethanol and 0.034\u2005mmol\u2009g\n                    <jats:sub>cat.<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    for formate acid), respectively. Mechanism studies indicate that the introduction of Pt species could create an active hydrogen\u2010rich environment, leading to the alterations of the adsorption configuration and conversion pathways of the *OCH\n                    <jats:sub>2<\/jats:sub>\n                    intermediates on Mo sites. As a result, the catalytic selectivity was successfully switched.\n                  <\/jats:p>","DOI":"10.1002\/anie.202407733","type":"journal-article","created":{"date-parts":[[2024,5,12]],"date-time":"2024-05-12T22:25:14Z","timestamp":1715552714000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Designing Dual\u2010Site Catalysts for Selectively Converting CO\n                    <sub>2<\/sub>\n                    into Methanol"],"prefix":"10.1002","volume":"63","author":[{"given":"Wenjie","family":"Cui","sequence":"first","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuou","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaomei","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7758-752X","authenticated-orcid":false,"given":"Shuyan","family":"Song","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongjie","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"},{"name":"Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,19]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-018-0167-5"},{"key":"e_1_2_7_3_2","author":"Li Y.","year":"2024","journal-title":"Angew. 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