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In particular, the development of more practical, and durable iron\u2010based materials is of central interest for organic synthesis, especially for the preparation of chemical products related to life science applications. Here, we report the preparation of Fe\u2010single atom catalysts (Fe\u2010SACs) entrapped in N\u2010doped mesoporous carbon support with unprecedented potential in the preparation of different kinds of amines, which represent privileged class of organic compounds and find increasing application in daily life. The optimal Fe\u2010SACs allow for the reductive amination of a broad range of aldehydes and ketones with ammonia and amines to produce diverse primary, secondary, and tertiary amines including N\u2010methylated products as well as drugs, agrochemicals, and other biomolecules (amino acid esters and amides) utilizing green hydrogen.<\/jats:p>","DOI":"10.1002\/anie.202407859","type":"journal-article","created":{"date-parts":[[2024,6,24]],"date-time":"2024-06-24T06:25:23Z","timestamp":1719210323000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Development of Iron\u2010Based Single Atom Materials for General and Efficient Synthesis of Amines"],"prefix":"10.1002","volume":"63","author":[{"given":"Zhuang","family":"Ma","sequence":"first","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.V.  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