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This achievement involved the condensation of six equivalents of enantiomerically pure <jats:italic>trans<\/jats:italic>\u2010cyclohexane\u20101,2\u2010diamine (<jats:italic>trans<\/jats:italic>\u2010CHDA) and three equivalents of the corresponding tetraformyl precursor. Each precursor was equipped with a luminescent linker terminated by two <jats:italic>m<\/jats:italic>\u2010phthalaldehyde units. Even though these tetraformyl precursors are barely soluble in almost all organic solvents, the molecular tubes are highly soluble in nonpolar solvents such as chloroform, allowing us to fully characterize them in solution. The stereo\u2010chirality of the chiral bisamino building blocks endows the frameworks of molecular tubes with planar chirality. As a consequence, all of these molecular tubes exhibit circularly polarized luminescence (CPL) with relatively large dissymmetry values |<jats:italic>g<\/jats:italic><jats:sub>lum<\/jats:sub>| up to 7\u00d710<jats:sup>\u22123<\/jats:sup>, providing an efficient method for synthesizing CPL\u2010active materials.<\/jats:p>","DOI":"10.1002\/anie.202408056","type":"journal-article","created":{"date-parts":[[2024,5,17]],"date-time":"2024-05-17T13:19:36Z","timestamp":1715951976000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Self\u2010Assembled Pure Covalent Tubes Exhibiting Circularly Polarized Luminescence"],"prefix":"10.1002","volume":"63","author":[{"given":"Chenqi","family":"Ge","sequence":"first","affiliation":[{"name":"Department of Chemistry Zhejiang University  Hangzhou 310058 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