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Recently, strategies for chiral phosphine catalysis under P\n                    <jats:sup>III<\/jats:sup>\n                    \/P\n                    <jats:sup>V<\/jats:sup>\n                    =O redox cycling emerged to render this venerable transformation stereoselective. Herein, we describe that phosphine redox catalysis enables the enantioselective synthesis of pertinent biaryl atropisomers by means of a stereocontrolled arene\u2010forming Wittig reaction. Key to the process is the release of an endogenous base from readily accessible\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butyloxycarbonylated Morita\u2013Baylis\u2013Hillman adducts triggered by catalyst intramolecularization, permitting mild phosphine redox catalysis for atroposelective Wittig reactions. By this strategy, a broad diversity of biaryl atropisomers is obtained with up to 94\u2009:\u20096 enantioselectivity.\n                  <\/jats:p>","DOI":"10.1002\/anie.202408159","type":"journal-article","created":{"date-parts":[[2024,6,28]],"date-time":"2024-06-28T13:52:52Z","timestamp":1719582772000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Atroposelective Arene\u2010Forming Wittig Reaction by Phosphorus P\n                    <sup>III<\/sup>\n                    \/P\n                    <sup>V<\/sup>\n                    =O Redox Catalysis"],"prefix":"10.1002","volume":"63","author":[{"given":"Kalipada","family":"Jana","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Basel  St. Johanns-Ring 19 4056 Basel Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengxing","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of 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