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Herein, we report electron\u2010deficient tetrahedral Co(II) (T\n                    <jats:sub>d<\/jats:sub>\n                    \u2010cobalt(II)) centers through carbon\u2010layer modulation for propane dehydrogenation (PDH). It is indicated that bifunctional sites of both T\n                    <jats:sub>d<\/jats:sub>\n                    \u2010cobalt(II) and metallic\u2010cobalt are designed, and the in situ generated carbon through the disproportionation of CO on metallic\u2010cobalt can cover the inactive metallic\u2010cobalt and tailor d\u2010band of active T\n                    <jats:sub>d<\/jats:sub>\n                    \u2010cobalt(II) simultaneously. More importantly, the pre\u2010deposited carbon\u2010layer is proposed to decrease electron density of T\n                    <jats:sub>d<\/jats:sub>\n                    \u2010cobalt(II) and make d\u2010band center closer to Fermi level, consequently promotes C\u2212H activation in PDH reaction. This study provides new perspective for the utilization of inactive carbon as electronic promoters and unlocks new opportunity to fabricate efficient PDH and other heterogeneous catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202408391","type":"journal-article","created":{"date-parts":[[2024,6,21]],"date-time":"2024-06-21T09:59:47Z","timestamp":1718963987000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":56,"title":["Modifying the Charge\u2010Density of Tetrahedral Cobalt(II) Centers through Carbon\u2010Layer Modulation Promotes C\u2010H Activation in the Propane Dehydrogenation Reaction (PDH)"],"prefix":"10.1002","volume":"63","author":[{"given":"Zijun","family":"Huang","sequence":"first","affiliation":[{"name":"Faculty of Chemical Engineering Kunming University of Science and Technology  Kunming 650500 China"},{"name":"Faculty of Environmental Science and Engineering Kunming University of Science and 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