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However, their development is significantly retarded by electrolyte design due to free water corrosion. Herein, we report a layer intercalatable electrolyte (LIE) by introducing trimethyl phosphate (TMP) into traditional acidic electrolyte. Different from conventional role in batteries, the presence of TMP intriguingly achieves co\u2010intercalation of solvent molecules into the interlayer of anode materials, enabling a new working mechanism for proton reactions. The electrode corrosion was also strongly retarded with expanded electrochemical stability window. The half\u2010cell therefore showed an outstanding long\u2010term cycling stability with 91.0\u2009% capacity retention at 5\u2005A\u2009g<jats:sup>\u22121<\/jats:sup> after 5000\u2005cycles. Furthermore, the assembled full batteries can even deliver an ultra\u2010long lifetime with a capacity retention of 74.9\u2009% for 2\u2005months running at \u221220\u2009\u00b0C. This work provides new opportunities for electrolyte design of aqueous batteries.<\/jats:p>","DOI":"10.1002\/anie.202409871","type":"journal-article","created":{"date-parts":[[2024,7,2]],"date-time":"2024-07-02T14:09:51Z","timestamp":1719929391000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Realization of Long\u2010Life Proton Battery by Layer Intercalatable Electrolyte"],"prefix":"10.1002","volume":"63","author":[{"given":"Peilin","family":"Liang","sequence":"first","affiliation":[{"name":"School of Metallurgy Northeastern University  Shenyang 110819 P. R. China"},{"name":"State Key Laboratory of Rolling and Automation Northeastern University  Shenyang 110819, Liaoning P. R. China"},{"name":"Foshan Graduate School of Innovation Northeastern University  Foshan 528311, Guangdong P. R. 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