{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,5]],"date-time":"2026-11-05T11:50:00Z","timestamp":1793879400397,"version":"4.7.0"},"reference-count":47,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2024,10,25]],"date-time":"2024-10-25T00:00:00Z","timestamp":1729814400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22104043"],"award-info":[{"award-number":["22104043"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52341201"],"award-info":[{"award-number":["52341201"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018627","name":"Science and Technology Support Plan for Youth Innovation of Colleges and Universities of Shandong Province of China","doi-asserted-by":"publisher","award":["2022KJ097"],"award-info":[{"award-number":["2022KJ097"]}],"id":[{"id":"10.13039\/501100018627","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2022M721332"],"award-info":[{"award-number":["2022M721332"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2021QB002"],"award-info":[{"award-number":["ZR2021QB002"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,11,25]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Intramolecular charge separation driving force and linkage chemistry between building blocks are critical factors for enhancing the photocatalytic performance of metal\u2010covalent organic framework (MCOF) based photocatalyst. However, robust achieving both simultaneously has yet to be challenging despite ongoing efforts. Here we develop a fully \u03c0\u2010conjugated vinylene\u2010linked multivariate donor\u2010\u03c0\u2010acceptor MCOF (D\u2010\u03c0\u2010A, termed UJN\u20101) by integrating benzyl cyanides linker with multiple functional building blocks of electron\u2010rich triphenylamine and electron\u2010deficient copper\u2010cyclic trinuclear units (Cu\u2010CTUs) moieties, featuring with strong intramolecular charge separation driving force, extended conjugation degree of skeleton, and abundant active sites. The incorporation of Cu\u2010CTUs acceptor with electron\u2010withdrawing ability and concomitantly giant charge separation driving force can efficiently accelerate the photogenerated electrons transfer from triphenylamine to Cu\u2010CTUs, revealing by experiments and theoretical calculations. Benefiting from the synergistically effect of D\u2010\u03c0\u2010A configuration and vinylene linkage, the highly\u2010efficient charge spatial separation is achieved. Consequently, UJN\u20101 exhibits an excellent CO formation rate of 114.8\u2005\u03bcmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    in 4\u2005h without any co\u2010catalysts or sacrificial reagents under visible light, outperforming those analogous MCOFs with imine\u2010linked (UJN\u20102, 28.9\u2005\u03bcmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and vinylene\u2010linked COF without Cu\u2010CTU active sites (UJN\u20103, 50.0\u2005\u03bcmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), emphasizing the role of charge separation driving force and linkage chemistry in designing novel COFs\u2010based photocatalyst.\n                  <\/jats:p>","DOI":"10.1002\/anie.202409925","type":"journal-article","created":{"date-parts":[[2024,9,3]],"date-time":"2024-09-03T06:56:18Z","timestamp":1725346578000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":112,"title":["Vinylene\u2010Linked Donor\u2010\u03c0\u2010Acceptor Metal\u2010Covalent Organic Framework for Enhanced Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction"],"prefix":"10.1002","volume":"63","author":[{"given":"Shanshan","family":"Li","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9807-5769","authenticated-orcid":false,"given":"Chaomin","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haihan","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuwen","family":"Wang","sequence":"additional","affiliation":[{"name":"Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuai","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenwen","family":"Ding","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lina","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinghua","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, University of Jinan  Jinan 250022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,25]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306497"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11967"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301190"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43586-022-00181-z"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01102-3"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-024-00542-4"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309480"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208919"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c04993"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303346"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202110694"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11893"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303129"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311519"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC00924A"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI00353H"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.020.202000401"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00769"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs15325d"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00703"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311023"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202204326"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202309060"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-35467-z"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311999"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202104898"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302808"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313648"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trechm.2021.03.008"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123075"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2019.104088"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207695"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12705"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202960"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32449-z"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp20056a"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2022.118558"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05530"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.123837"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139378"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11987"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13817"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2023.156335"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202305900"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906890"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202109330"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313392"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202409925","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T02:00:52Z","timestamp":1739239252000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202409925"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,10,25]]},"references-count":47,"journal-issue":{"issue":"48","published-print":{"date-parts":[[2024,11,25]]}},"alternative-id":["10.1002\/anie.202409925"],"URL":"https:\/\/doi.org\/10.1002\/anie.202409925","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,10,25]]},"assertion":[{"value":"2024-05-26","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-10-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202409925"}}