{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T21:03:19Z","timestamp":1784149399771,"version":"3.55.0"},"reference-count":72,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2024,8,20]],"date-time":"2024-08-20T00:00:00Z","timestamp":1724112000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100019180","name":"HORIZON EUROPE European Research Council","doi-asserted-by":"publisher","award":["101077332"],"award-info":[{"award-number":["101077332"]}],"id":[{"id":"10.13039\/100019180","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100019180","name":"HORIZON EUROPE European Research Council","doi-asserted-by":"publisher","award":["772299"],"award-info":[{"award-number":["772299"]}],"id":[{"id":"10.13039\/100019180","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt-Stiftung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,9,16]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Diazoalkenes readily react with <jats:italic>tert<\/jats:italic>\u2010butylphosphaalkyne (<jats:italic>t<\/jats:italic>BuCP) and white phosphorus (P<jats:sub>4<\/jats:sub>) to afford novel phosphorus heterocycles, 3<jats:italic>H<\/jats:italic>\u20101,2,4\u2010diazamonophospholes and 1,2,3,4\u2010diazadiphospholes. Both species represent rare examples of neutral heterophospholes. The mechanism of formation and the electronic structures of these formal (3+2) cycloaddition products were analyzed computationally. The new phospholes form structurally diverse coordination compounds with transition metal and main group elements. Given the growing number of stable diazoalkenes, this work offers a straightforward route to neutral aza(di\u2010)phospholes as a new ligand class.<\/jats:p>","DOI":"10.1002\/anie.202410107","type":"journal-article","created":{"date-parts":[[2024,7,1]],"date-time":"2024-07-01T16:33:38Z","timestamp":1719851618000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Cycloadditions of Diazoalkenes with P<sub>4<\/sub> and <i>t<\/i>BuCP: Access to Diazaphospholes"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-9963-4751","authenticated-orcid":false,"given":"Sebastian","family":"Hauer","sequence":"first","affiliation":[{"name":"University of Regensburg Institute of Inorganic Chemistry  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Justus","family":"Reitz","sequence":"additional","affiliation":[{"name":"TU Dortmund Faculty of Chemistry and Chemical Biology  44227 Dortmund Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6713-4375","authenticated-orcid":false,"given":"Taichi","family":"Koike","sequence":"additional","affiliation":[{"name":"TU Dortmund Faculty of Chemistry and Chemical Biology  44227 Dortmund Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3107-1445","authenticated-orcid":false,"given":"Max M.","family":"Hansmann","sequence":"additional","affiliation":[{"name":"TU Dortmund Faculty of Chemistry and Chemical Biology  44227 Dortmund Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4066-6483","authenticated-orcid":false,"given":"Robert","family":"Wolf","sequence":"additional","affiliation":[{"name":"University of Regensburg Institute of Inorganic Chemistry  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,20]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b510917e"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003709"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202001854"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213927"},{"key":"e_1_2_3_8_1","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702067"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201004385"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_3_12_1","unstructured":"\u00a0"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703055"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902344"},{"key":"e_1_2_3_15_1","unstructured":"\u00a0"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja077296u"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc42041h"},{"key":"e_1_2_3_18_1","unstructured":"\u00a0"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00675-5"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00790-3"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c06906"},{"key":"e_1_2_3_22_1","first-page":"62","author":"Reitz J.","year":"2023","journal-title":"Angew. 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