{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T16:39:08Z","timestamp":1793291948992,"version":"4.5.0"},"reference-count":63,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2024,8,16]],"date-time":"2024-08-16T00:00:00Z","timestamp":1723766400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The catalytic activity of platinum for CO oxidation depends on the interaction of electron donation and back\u2010donation at the platinum center. Here we demonstrate that the platinum bromine nanoparticles with electron\u2010rich properties on bromine bonded with sp\u2010C in graphdiyne (PtBr NPs\/Br\u2010GDY), which is formed by bromine ligand and constitutes an electrocatalyst with a high CO\u2010resistant for methanol oxidation reaction (MOR). The catalyst showed peak mass activity for MOR as high as 10.4\u2005A\u2009mg\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is 20.8\u2005times higher than the 20\u2009% Pt\/C. The catalyst also showed robust long\u2010term stability with slight current density decay after 100\u2005hours at 35\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Structural characterization, experimental, and theoretical studies show that the electron donation from bromine makes the surface of platinum catalysts highly electron\u2010rich, and can strengthen the adsorption of CO as well as enhance \u03c0 back\u2010donation of Pt to weaken the C\u2212O bond to facilitate CO electrooxidation and enhance catalytic performance during MOR. The results highlight the importance of electron\u2010rich structure among active sites in Pt\u2010halogen catalysts and provide detailed insights into the new mechanism of CO electrooxidation to overcome CO poisoning at the Pt center on an orbital level.\n                  <\/jats:p>","DOI":"10.1002\/anie.202410413","type":"journal-article","created":{"date-parts":[[2024,7,8]],"date-time":"2024-07-08T04:19:35Z","timestamp":1720412375000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":57,"title":["Halogen Tailoring of Platinum Electrocatalyst with High CO Tolerance for Methanol Oxidation Reaction"],"prefix":"10.1002","volume":"63","author":[{"given":"Lan","family":"Hui","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Organic Solids, Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P. R. 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