{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,7]],"date-time":"2026-11-07T02:31:15Z","timestamp":1794018675117,"version":"4.8.0"},"reference-count":77,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2024,8,13]],"date-time":"2024-08-13T00:00:00Z","timestamp":1723507200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Rational design of efficient methanol oxidation reaction (MOR) catalyst that undergo non\u2010CO pathway is essential to resolve the long\u2010standing poisoning issue. However, it remains a huge challenge due to the rather difficulty in maximizing the non\u2010CO pathway by the selective coupling between the key *CHO and *OH intermediates. Here, we report a high\u2010performance electrocatalyst of patchy atomic\u2010layer Pt epitaxial growth on CeO\n                    <jats:sub>2<\/jats:sub>\n                    nanocube (Pt ALs\/CeO\n                    <jats:sub>2<\/jats:sub>\n                    ) with maximum electronic metal\u2010support interaction for enhancing the coupling selectively. The small\u2010size monolayer material achieves an optimal geometrical distance between edge Pt\u2212O\u2212Ce sites and *OH absorbed on CeO\n                    <jats:sub>2<\/jats:sub>\n                    , which well restrains the dehydrogenation of *CHO, resulting in the non\u2010CO pathway. Meanwhile, the *CHO\/*CO intermediate generated at inner Pt\u2212O\u2212Ce sites can migrate to edge, inducing the subsequent coupling reaction, thus avoiding poisoning while promoting reaction efficiency. Consequently, Pt ALs\/CeO\n                    <jats:sub>2<\/jats:sub>\n                    exhibits exceptionally catalytic stability with negligible degradation even under 1000\u2005s pure CO poisoning operation and high mass activity (14.87\u2005A\/mg\n                    <jats:sub>Pt<\/jats:sub>\n                    ), enabling it one of the best\u2010performing alkali\u2010stable MOR catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202410545","type":"journal-article","created":{"date-parts":[[2024,6,28]],"date-time":"2024-06-28T07:43:53Z","timestamp":1719560633000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":76,"title":["Edge\u2010Rich Pt\u2212O\u2212Ce Sites in CeO\n                    <sub>2<\/sub>\n                    Supported Patchy Atomic\u2010Layer Pt Enable a Non\u2010CO Pathway for Efficient Methanol Oxidation"],"prefix":"10.1002","volume":"63","author":[{"given":"Airong","family":"Xu","sequence":"first","affiliation":[{"name":"School of Nuclear Science and Technology Key Laboratory of Precision and Intelligent Chemistry Hefei National Research Center for Physical Sciences at the Microscale National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei P.R. 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