{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T02:17:50Z","timestamp":1791685070471,"version":"4.3.4"},"reference-count":57,"publisher":"Wiley","issue":"50","license":[{"start":{"date-parts":[[2024,11,27]],"date-time":"2024-11-27T00:00:00Z","timestamp":1732665600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFB3506600"],"award-info":[{"award-number":["2023YFB3506600"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,12,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Low dimensional organic\u2010inorganic hybrid metal halide materials have attracted extensive attention due to their superior optoelectronic properties. However, low photoluminescence quantum yields (PLQYs) caused by parity\u2010forbidden transition hinder their further application in optoelectronic devices. Herein, a novel yellow\u2010emitting PMA\n                    <jats:sub>4<\/jats:sub>\n                    Na(In,Sb)Cl\n                    <jats:sub>8<\/jats:sub>\n                    (C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>10<\/jats:sub>\n                    N\n                    <jats:sup>+<\/jats:sup>\n                    , PMA\n                    <jats:sup>+<\/jats:sup>\n                    ) low\u2010dimensional OIMHs single crystal with a PLQY as high as 88\u2009% was successfully designed and synthesized, originating from the fact that the doping of Sb\n                    <jats:sup>3+<\/jats:sup>\n                    effectively relaxes the parity\u2010forbidden transition by strong spin\u2010orbit (SO) coupling and Jahn\u2010Teller (JT) interaction. The as\u2010prepared crystal shows an efficient dual emission peaking 495 and 560\u2005nm at low temperature, which are ascribed to different levels of\n                    <jats:sup>3<\/jats:sup>\n                    P\n                    <jats:sub>1<\/jats:sub>\n                    \u2192\n                    <jats:sup>1<\/jats:sup>\n                    S\n                    <jats:sub>0<\/jats:sub>\n                    transitions of Sb\n                    <jats:sup>3+<\/jats:sup>\n                    in [SbCl\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>3\u2212<\/jats:sup>\n                    octahedral caused by JT deformation. Moreover, wide\u2010range luminescence tailoring from cyan to orange can be achieved through adjusting excitation energy and temperature because of flexible [SbCl\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>3\u2212<\/jats:sup>\n                    octahedral in the PNIC lattice. Based on a relative stiff lattice environment, the 560\u2005nm yellow emission under 350\u2005nm light excitation exhibits abnormal anti\u2010thermal quenching from 8 to 400\u2005K owing to the suppression of non\u2010radiative transition. The multimode luminescence regulation enriches PMA\n                    <jats:sub>4<\/jats:sub>\n                    Na(In,Sb)Cl\n                    <jats:sub>8<\/jats:sub>\n                    great potential in the field of optoelectronics such as temperature sensing, low temperature anti\u2010counterfeiting and WLED applications.\n                  <\/jats:p>","DOI":"10.1002\/anie.202411136","type":"journal-article","created":{"date-parts":[[2024,8,15]],"date-time":"2024-08-15T22:19:33Z","timestamp":1723760373000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":59,"title":["Multimode Luminescence Tailoring in PMA\n                    <sub>4<\/sub>\n                    Na(In,Sb)Cl\n                    <sub>8<\/sub>\n                    Organic\u2013inorganic Hybrid Metal Halide via Rigid Benzene Ring Induced Local Lattice Distortion"],"prefix":"10.1002","volume":"63","author":[{"given":"Wei","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peipei","family":"Dang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guodong","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongjie","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingsheng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Wei","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Chemistry China University of Geosciences  Wuhan 430074 China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongzhou","family":"Lian","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guogang","family":"Li","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Chemistry China University of Geosciences  Wuhan 430074 China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9572-2134","authenticated-orcid":false,"given":"Jun","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 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