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This process predominantly utilizes 3\u2010dimensional 10\u2010member ring (10\u2010MR) zeolites like ZSM\u20105 and ZSM\u201011, chosen for their confinement effect essential for aromatization. Current research mainly focuses on enhancing selectivity and mitigating catalyst deactivation by modulating zeolites\u2032 physicochemical properties. Despite the potential, the MTA technology is at a low Technology Readiness Level, hindered by mechanistic complexities in achieving the desired selectivity towards liquid aromatics. To bridge this knowledge gap, this study proposes a roadmap for MTA catalysis by strategically combining controlled catalytic experiments with advanced characterization methods (including operando conditions and \u201cmobility\u2010dependent\u201d solid\u2010state NMR spectroscopy). It identifies the descriptor\u2010role of Koch\u2010carbonylated intermediates, longer\u2010chain hydrocarbons, and the zeolites\u2032 intersectional cavities in yielding preferential liquid aromatics selectivity. Understanding these selectivity descriptors and architectural impacts is vital, potentially advancing other zeolite\u2010catalyzed emerging technologies.<\/jats:p>","DOI":"10.1002\/anie.202411197","type":"journal-article","created":{"date-parts":[[2024,6,27]],"date-time":"2024-06-27T18:56:57Z","timestamp":1719514617000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Selectivity Descriptors of Methanol\u2010to\u2010Aromatics Process over 3\u2010Dimensional Zeolites"],"prefix":"10.1002","author":[{"given":"Xin","family":"Zhang","sequence":"first","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  430072 Wuhan Hubei, P.\u2005R. 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