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A high\u2010pressure high\u2010temperature reaction (8\u2005GPa, 1400\u2009\u00b0C) of Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    and P\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    with NH\n                    <jats:sub>4<\/jats:sub>\n                    F as a mineralizing agent yields the compound in the form of black, rod\u2010shaped crystals. Single\u2010crystal X\u2010ray structure elucidation (space group\n                    <jats:italic>C<\/jats:italic>\n                    2\/\n                    <jats:italic>m<\/jats:italic>\n                    (no. 12),\n                    <jats:italic>a<\/jats:italic>\n                    =16.202(3),\n                    <jats:italic>b<\/jats:italic>\n                    =2.9155(4),\n                    <jats:italic>c<\/jats:italic>\n                    =11.089(2)\u2005\u00c5,\n                    <jats:italic>\u03b2<\/jats:italic>\n                    =126.698(7)\u00b0,\n                    <jats:italic>Z<\/jats:italic>\n                    =2) shows a network of face\u2010 and edge\u2010sharing Ta\u2010centered polyhedra that contains small vacant channels and PN\n                    <jats:sub>6<\/jats:sub>\n                    octahedra strands. Atomic resolution transmission electron microscopy reveals an unusual P\/Ta disorder. Mixed\u2010valent tantalum atoms exhibit interatomic distances similar to those in metallic tantalum, however, the electrical resistivity is quite high in the order of 10\n                    <jats:sup>1<\/jats:sup>\n                    \u2005\u03a9\u2009cm. The density of states and the electron localization function indicate localized electrons in both covalent and ionic bonds between P\/Ta and N atoms, combined with less localized electrons that do not contribute to interatomic bonds.\n                  <\/jats:p>","DOI":"10.1002\/anie.202411441","type":"journal-article","created":{"date-parts":[[2024,7,23]],"date-time":"2024-07-23T06:55:02Z","timestamp":1721717702000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["P\n                    <sub>\n                      1\u2212\n                      <i>x<\/i>\n                    <\/sub>\n                    Ta\n                    <sub>\n                      8+\n                      <i>x<\/i>\n                    <\/sub>\n                    N\n                    <sub>13<\/sub>\n                    (\n                    <i>x<\/i>\n                    =0.1\u20130.15): A Phosphorus Tantalum Nitride Featuring Mixed\u2010Valent Tantalum and P\/Ta Disorder Visualized by Scanning Transmission Electron Microscopy"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6787-8454","authenticated-orcid":false,"given":"Monika M.","family":"Pointner","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7684-788X","authenticated-orcid":false,"given":"Claude","family":"Ceniza","sequence":"additional","affiliation":[{"name":"Department of Physics and Engineering Physics University of Saskatchewan  116 Science Place Saskatoon, Saskatchewan S7N 5E2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lukas","family":"Nusser","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich 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