{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T22:39:17Z","timestamp":1792103957902,"version":"4.4.0"},"reference-count":72,"publisher":"Wiley","issue":"52","license":[{"start":{"date-parts":[[2024,11,7]],"date-time":"2024-11-07T00:00:00Z","timestamp":1730937600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,11,7]],"date-time":"2024-11-07T00:00:00Z","timestamp":1730937600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,12,20]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Alcohols carbonylation is of great importance in industry but remains a challenge to abandon the usage of the halide additives and noble metals. Here we report the realization of direct alcohols heterogeneous carbonylation to carbonyl\u2010containing chemicals, especially in methanol carbonylation, with a remarkable space\u2010time\u2010yield (STY) of 4.74 mol\n                    <jats:sub>acetyl<\/jats:sub>\n                    \/kg\n                    <jats:sub>cat.<\/jats:sub>\n                    \/h and a durable stability as long as 100\u2005h on Ni@MoS\n                    <jats:sub>2<\/jats:sub>\n                    catalyst. Mechanistic analysis reveals that the Mo\u2212Ni dual sites localized at edge sulfur vacancies of Ni@MoS\n                    <jats:sub>2<\/jats:sub>\n                    exhibit distinct charge density, which strongly activate CH\n                    <jats:sub>3<\/jats:sub>\n                    OH to break its C\u2212O bond and non\u2010dissociatively activate CO. Density functional theory calculations further suggest that the low charge density in Mo\u2212Ni, the Ni site, could significantly lower the barrier for CO migration and nucleophilic attack of methoxy species, and finally leads to the rapid formation of acetyl products. Ni@MoS\n                    <jats:sub>2<\/jats:sub>\n                    catalyst could also effectively realize the carbonylation of ethanol, n\u2010propanol and n\u2010butanol to their acyl products, which may demonstrate its universal application for alcohols carbonylation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202411632","type":"journal-article","created":{"date-parts":[[2024,9,26]],"date-time":"2024-09-26T23:23:58Z","timestamp":1727393038000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Heterogeneous Carbonylation of Alcohols on Charge\u2010Density\u2010Distinct Mo\u2212Ni Dual Sites Localized at Edge Sulfur Vacancies"],"prefix":"10.1002","volume":"63","author":[{"given":"Qiao","family":"Yuan","sequence":"first","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"},{"name":"University of Chinese Academy of Sciences  100049 Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yating","family":"Gu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Mesoscopic Chemistry of Ministry of Education School of Chemistry and Chemical Engineering Nanjing University  210023 Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weimiao","family":"Chen","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Zhang","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"},{"name":"University of Chinese Academy of Sciences  100049 Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangen","family":"Song","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangming","family":"Ding","sequence":"additional","affiliation":[{"name":"University of Chinese Academy of Sciences  100049 Beijing China"},{"name":"CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  116023 Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingju","family":"Li","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Zhu","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zheng","family":"Jiang","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility Shanghai Institute of Applied Physics Shanghai Advanced Research Institute Chinese Academy of Sciences  201204 Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Yan","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Ma","sequence":"additional","affiliation":[{"name":"Key Laboratory of Mesoscopic Chemistry of Ministry of Education School of Chemistry and Chemical Engineering Nanjing University  210023 Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8894-9648","authenticated-orcid":false,"given":"Yunjie","family":"Ding","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian  116023 Liaoning China"},{"name":"State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  116023 Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,7]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1007\/3418_021"},{"key":"e_1_2_7_3_2","first-page":"1","volume-title":"Advances in Catalysis, Vol.\u200553","author":"Haynes A.","year":"2010"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.213078"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527618231.ch2a"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1134\/S107042722208002X"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2020.117488"},{"key":"e_1_2_7_9_1","unstructured":"\u00a0"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(01)00800-6"},{"key":"e_1_2_7_11_2","doi-asserted-by":"crossref","unstructured":"Chem. Eng. News Archive1971 49 19 https:\/\/doi.org\/10.1021\/cen-v049n035.p019.","DOI":"10.1021\/cen-v049n049.p019"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9960002187"},{"key":"e_1_2_7_13_1","unstructured":"\u00a0"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060282x"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00328A"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.ade3179"},{"key":"e_1_2_7_17_1","unstructured":"\u00a0"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03933"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201904976"},{"key":"e_1_2_7_20_1","unstructured":"\u00a0"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2019.04.015"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0166-1280(00)00859-9"},{"key":"e_1_2_7_23_1","unstructured":"\u00a0"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs3000528"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2021.118263"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CY00254J"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.9b02289"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05026"},{"key":"e_1_2_7_29_1","unstructured":"\u00a0"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1984.2047"},{"key":"e_1_2_7_31_2","first-page":"771","volume-title":"Stud. Surf. Sci. Catal., Vol.\u2005101","author":"Ellis B.","year":"1996"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01621B"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY01321K"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CY00460H"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c05185"},{"key":"e_1_2_7_36_1","unstructured":"\u00a0"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003484"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42325-z"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c00596"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms14430"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06628"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202102886"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216347"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402176"},{"key":"e_1_2_7_46_1","unstructured":"\u00a0"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2740"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00584-3"},{"key":"e_1_2_7_49_1","unstructured":"\u00a0"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA03166E"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1109997"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1038\/srep12869"},{"key":"e_1_2_7_53_1","unstructured":"\u00a0"},{"key":"e_1_2_7_54_2","author":"Sun T.","year":"2023","journal-title":"Nat. Nanotechnol."},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.08.041"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17199-0"},{"key":"e_1_2_7_57_1","unstructured":"\u00a0"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10551"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03669"},{"key":"e_1_2_7_60_1","unstructured":"\u00a0"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0360-0564(08)60658-6"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp0462052"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp961204y"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1098\/rspa.1934.0209"},{"key":"e_1_2_7_65_1","unstructured":"\u00a0"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF00812471"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY00719A"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2004.06.058"},{"key":"e_1_2_7_69_1","first-page":"81","volume-title":"Advances in Catalysis, Vol.\u200534","author":"Dekleva T. W.","year":"1986"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00020a039"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.3c00558"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01555"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202411632","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202411632","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202411632","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,25]],"date-time":"2026-05-25T14:28:03Z","timestamp":1779719283000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202411632"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,7]]},"references-count":72,"journal-issue":{"issue":"52","published-print":{"date-parts":[[2024,12,20]]}},"alternative-id":["10.1002\/anie.202411632"],"URL":"https:\/\/doi.org\/10.1002\/anie.202411632","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,7]]},"assertion":[{"value":"2024-06-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202411632"}}