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However, its practical application still faces significant challenges, including high energy consumption, poor selectivity, and limited stability. Here, we propose a hybrid acid\/alkali electrolyzer that couples the acidic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) at the cathode with alkaline methanol oxidation reaction (MOR) at the anode. This dual electro\u2010synthesis cell is implemented by developing Bi nanosheets as cathode catalysts and oxide\u2010decorated Cu\n                    <jats:sub>2<\/jats:sub>\n                    Se nanoflowers as anode catalysts, enabling high\u2010efficiency electron utilization for formate production with over 180\u2009% coulombic efficiency and more than 90\u2009% selectivity for both CO\n                    <jats:sub>2<\/jats:sub>\n                    RR and MOR conversion. The hybrid acid\/alkali CO\n                    <jats:sub>2<\/jats:sub>\n                    RR\u2010MOR cell also demonstrates long\u2010term stability exceeding 90\u2005hours of continuous operation, delivers a formate partial current density of 130\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at a voltage of only 2.1\u2005V, and significantly reduces electricity consumption compared to the traditional CO\n                    <jats:sub>2<\/jats:sub>\n                    electrolysis system. This study illuminates an innovative electron\u2010efficiency and energy\u2010saving techniques for CO\n                    <jats:sub>2<\/jats:sub>\n                    electrolysis, as well as the development of highly efficient electrocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202412410","type":"journal-article","created":{"date-parts":[[2024,8,1]],"date-time":"2024-08-01T10:43:50Z","timestamp":1722509030000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Electron\u2010Efficient Co\u2010Electrosynthesis of Formates from CO\n                    <sub>2<\/sub>\n                    and Methanol Feedstocks"],"prefix":"10.1002","volume":"63","author":[{"given":"Xin","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Provincial Key Laboratory of Material and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou Fujian China"},{"name":"College of Chemistry and Materials Science Fujian Normal University  350002 Fuzhou Fujian China"},{"name":"Fujian College University of Chinese Academy of Sciences  350002 Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingsong","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Provincial Key Laboratory of Material and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou Fujian China"},{"name":"College of Chemistry and Materials Science Fujian Normal University  350002 Fuzhou Fujian China"},{"name":"Fujian College University of Chinese Academy of Sciences  350002 Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Provincial Key Laboratory of Material and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou Fujian China"},{"name":"Fujian College University of Chinese Academy of Sciences  350002 Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengchao","family":"He","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Provincial Key Laboratory of Material and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2340-9525","authenticated-orcid":false,"given":"Zhenhai","family":"Wen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Provincial Key Laboratory of Material and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou Fujian China"},{"name":"Fujian College University of Chinese Academy of Sciences  350002 Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,9,17]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008631"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202105246"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00489"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37441-9"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202100134"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2021.106751"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0374-6"},{"key":"e_1_2_7_9_1","author":"Chen Y.","year":"2023","journal-title":"Nat. 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