{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T21:19:52Z","timestamp":1792790392647,"version":"4.5.0"},"reference-count":47,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2024,11,11]],"date-time":"2024-11-11T00:00:00Z","timestamp":1731283200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52172256"],"award-info":[{"award-number":["52172256"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52372248"],"award-info":[{"award-number":["52372248"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,1,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The direct conversion and efficient utilization of methane pose a critical scientific challenge. Indirect activation via reactive oxygen species (ROS) offers a high probability of contact with methane and conversion efficiency under mild conditions. However, reported product yields are suboptimal due to challenges in activating oxygen and facilitating mass transfer in suspension systems. We propose the use of contact\u2010electro\u2010catalysis (CEC), employing polydopamine (PDA) as a catalyst that undergoes electron transfer with oxygen under ultrasound, generating ROS that drives the partial oxidation of methane (POM). Corresponding experimental results indicate that CH<jats:sub>3<\/jats:sub>OH and most HCHO are produced directly from CH<jats:sub>4<\/jats:sub>. Furthermore, through in situ characterizations, we have shown that light pretreatment of the catalysts in an oxygenated atmosphere facilitates the forming of more C=O functional groups with strong electron\u2010withdrawing properties, thereby significantly enhancing overall product yields, particularly for CH<jats:sub>3<\/jats:sub>OH. Within two hours, product yields reach 1.5\u2005mmol\u2009g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup> for HCHO and 0.9\u2005mmol\u2009g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup> for CH<jats:sub>3<\/jats:sub>OH. This work introduces a novel approach for efficient POM, while highlighting the distinctive catalytic properties of PDA.<\/jats:p>","DOI":"10.1002\/anie.202413343","type":"journal-article","created":{"date-parts":[[2024,10,17]],"date-time":"2024-10-17T04:15:50Z","timestamp":1729138550000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Polydopamine\u2010Mediated Contact\u2010Electro\u2010Catalysis for Efficient Partial Oxidation of Methane"],"prefix":"10.1002","volume":"64","author":[{"given":"Taikang","family":"Jia","sequence":"first","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  1295 Dingxi Road Shanghai 200050 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  19 Yuquan Road Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjing","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  1295 Dingxi Road Shanghai 200050 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  19 Yuquan Road Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanqi","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  1295 Dingxi Road Shanghai 200050 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  19 Yuquan Road Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4991-1134","authenticated-orcid":false,"given":"Ling","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  1295 Dingxi Road Shanghai 200050 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  19 Yuquan Road Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5983-3937","authenticated-orcid":false,"given":"Wenzhong","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  1295 Dingxi Road Shanghai 200050 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  19 Yuquan Road Beijing 100049 China"},{"name":"School of Chemistry and Materials Science Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences  1 Sub-lane Xiangshan Hangzhou 310024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,11]]},"reference":[{"key":"e_1_2_8_1_1","author":"Jiang Y.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202301279"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.05.008"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00783A"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2206619120"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-022-00422-3"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301118"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11440"},{"key":"e_1_2_8_9_1","author":"Wang Z.","year":"2024","journal-title":"Chem. Soc. Rev."},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-023-01238-8"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6633\/ac0a50"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-14278-9"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45041-4"},{"key":"e_1_2_8_14_1","author":"Wang Y.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00782C"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c05365"},{"key":"e_1_2_8_17_1","author":"Deng Y.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.3c06197"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202200113"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49663-6"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305747"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1147241"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400407a"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssb.201800308"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201600443"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202301678"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aaq1293"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2014.03.028"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/la5026608"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2021.102193"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-08454-0"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201403709"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00374G"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04884"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13648"},{"key":"e_1_2_8_36_1","author":"Li W.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2024.115289"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32984-9"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.actbio.2019.02.032"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03288"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2016.12.189"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.9b01474"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2023.139922"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7PY00051K"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44586-0"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2021.106369"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.147931"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202413343","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,15]],"date-time":"2025-05-15T08:19:08Z","timestamp":1747297148000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202413343"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,11]]},"references-count":47,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2025,1,2]]}},"alternative-id":["10.1002\/anie.202413343"],"URL":"https:\/\/doi.org\/10.1002\/anie.202413343","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,11]]},"assertion":[{"value":"2024-07-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202413343"}}