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However, challenges like polyiodide shuttle effect and Zn dendrite growth hinder their practical application. Here, we report a cation exchange membrane to simultaneously prevent the polyiodide shuttle effect and regulate Zn\n                    <jats:sup>2+<\/jats:sup>\n                    deposition. Comprised of rigid polymers, this membrane shows superior swelling resistance and ion selectivity compared to commercial Nafion. The resulting Zn\u2212I\n                    <jats:sub>2<\/jats:sub>\n                    battery exhibits a high Coulombic efficiency of 99.4\u2009% and low self\u2010discharge rate of 4.47\u2009% after 48\u2005h rest. By directing a uniform Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux, the membrane promotes a homogeneous electric field, resulting in a dendrite\u2010free Zn surface. Moreover, its microporous structure enables pre\u2010adsorption of additional active materials prior to battery assembly, boosting battery capacity to 287\u2005mAh\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1\u2005A\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . At 2\u2005A\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , the battery exhibits a steady running for 10,000\u2005cycles with capacity retention up to 96.1\u2009%, demonstrating high durability of the membrane. The practicality of the membrane is validated via a high\u2010loading (35\u2005mg\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) pouch cell with impressive cycling stability, paving a way for membrane design towards advanced Zn\u2212I\n                    <jats:sub>2<\/jats:sub>\n                    batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.202413703","type":"journal-article","created":{"date-parts":[[2024,8,16]],"date-time":"2024-08-16T10:24:40Z","timestamp":1723803880000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":78,"title":["Anti\u2010Swelling Microporous Membrane for High\u2010Capacity and Long\u2010Life Zn\u2212I\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Qianru","family":"Chen","sequence":"first","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  5005 Adelaide SA Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junnan","family":"Hao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  5005 Adelaide SA Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilong","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  5005 Adelaide SA Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shao\u2010Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  5005 Adelaide SA Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peipei","family":"Zuo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry School of Chemistry and Materials Science University of Science and Technology of China  230026 Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xun","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  5005 Adelaide SA Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mietek","family":"Jaroniec","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry &amp; Advanced Materials and Liquid Crystal Institute Kent State University  44242 Kent OH United States of America"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4568-8422","authenticated-orcid":false,"given":"Shi\u2010Zhang","family":"Qiao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  5005 Adelaide SA Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,17]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016531"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202102701"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-022-00511-3"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206963"},{"key":"e_1_2_8_6_1","unstructured":"\u00a0"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202201716"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.2c00460"},{"key":"e_1_2_8_9_1","unstructured":"\u00a0"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-00649-7"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09445"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.09.028"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c01310"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-017-1920-9"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202006897"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202105063"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300922"},{"key":"e_1_2_8_18_1","unstructured":"\u00a0"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.131283"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c05283"},{"key":"e_1_2_8_21_1","unstructured":"\u00a0"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202001997"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC00792A"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202210043"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202300656"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202310284"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202309038"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2023.122130"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms7303"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00804-x"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(94)02206-Q"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201605916"},{"key":"e_1_2_8_33_1","unstructured":"\u00a0"},{"key":"e_1_2_8_34_2","first-page":"647","volume-title":"Handbook of Fuel Cells \u2013 Fundamentals, Technology and Applications, Vol.\u20053","author":"LaConti A. 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