{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T16:58:58Z","timestamp":1790787538981,"version":"4.1.0"},"reference-count":32,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2024,11,16]],"date-time":"2024-11-16T00:00:00Z","timestamp":1731715200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,11,16]],"date-time":"2024-11-16T00:00:00Z","timestamp":1731715200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["19H05463"],"award-info":[{"award-number":["19H05463"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["22K21346"],"award-info":[{"award-number":["22K21346"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100008608","name":"Sumitomo Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100008608","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,1,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Herein, we report the synthesis of double\u2010walled noncovalent carbon nanotubes (CNTs) through host\u2013guest complexation of nanotube fragments and tube\u2010forming crystal engineering. As the smallest fragment of double\u2010walled CNTs, a host\u2013guest complex of perfluorocycloparaphenylene (PFCPP) and carbon nanobelt (CNB) was synthesized by mixing them in solvents. The immediate complexation of the PF[12]CPP\u2e27(6,6)CNB complex with a remarkably high association constant (\n                    <jats:italic>K<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    ) of 2\u00d710\n                    <jats:sup>5<\/jats:sup>\n                    \u2005L\/mol was observed. Time\u2010dependent\n                    <jats:sup>1<\/jats:sup>\n                    H NMR and thermogravimetry measurements revealed that the stability of (6,6)CNB was significantly improved by encapsulation. X\u2010ray crystallography confirmed the robust belt\u2010in\u2010ring structure of this complex. As indicated by the short distance between PF[12]CPP and (6,6)CNB (2.8\u2005\u00c5), intermolecular orbital interactions exist between the belt and the ring, which were further supported by theoretical calculation and phosphorescence quenching experiments. While the PF[12]CPP\u2e27(6,6)CNB complex adopts various crystal packing structures, chloroform was discovered to be a magic \u201cglue\u201d solvent inducing one\u2010dimensional alignment of the PF[12]CPP\u2e27(6,6)CNB complex to build an unprecedented double\u2010walled noncovalent CNT structure.\n                  <\/jats:p>","DOI":"10.1002\/anie.202413828","type":"journal-article","created":{"date-parts":[[2024,10,23]],"date-time":"2024-10-23T10:00:46Z","timestamp":1729677646000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["A Double\u2010walled Noncovalent Carbon Nanotube by Columnar Packing of Nanotube Fragments"],"prefix":"10.1002","volume":"64","author":[{"given":"Daiki","family":"Imoto","sequence":"first","affiliation":[{"name":"Department of Chemistry Graduate School of Science Nagoya University, Chikusa  Nagoya 464-8602 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroki","family":"Shudo","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Nagoya University, Chikusa  Nagoya 464-8602 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Akiko","family":"Yagi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Nagoya University, Chikusa  Nagoya 464-8602 Japan"},{"name":"Institute of Transformative Bio-Molecules (WPI-ITbM) Nagoya University, Chikusa  Nagoya 464-8602 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5227-7894","authenticated-orcid":false,"given":"Kenichiro","family":"Itami","sequence":"additional","affiliation":[{"name":"Institute of Transformative Bio-Molecules (WPI-ITbM) Nagoya University, Chikusa  Nagoya 464-8602 Japan"},{"name":"Molecule Creation Laboratory RIKEN Cluster for Pioneering Research  RIKEN Wako Saitama 351-0198 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,16]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/354056a0"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2008.364"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/433476a"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0NR00620C"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(01)01127-7"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn103263b"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja807126u"},{"key":"e_1_2_3_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902617"},{"key":"e_1_2_3_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905659"},{"key":"e_1_2_3_10_1","unstructured":"\u00a0"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00366G"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508384"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-019-0140-0"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.1c00105"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aam8158"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/prechem.3c00083"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201700097"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NR08931A"},{"key":"e_1_2_3_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.3c05644"},{"key":"e_1_2_3_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.9b02340"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b02715"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC03561A"},{"key":"e_1_2_3_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31530-x"},{"key":"e_1_2_3_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC04887J"},{"key":"e_1_2_3_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0sm01559h"},{"key":"e_1_2_3_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/366324a0"},{"key":"e_1_2_3_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar400030e"},{"key":"e_1_2_3_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.2c00062"},{"key":"e_1_2_3_29_1","unstructured":"CCDC numbers: 2371687 2371688 and 2371689."},{"key":"e_1_2_3_30_1","doi-asserted-by":"publisher","DOI":"10.1246\/cl.170210"},{"key":"e_1_2_3_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703648"},{"key":"e_1_2_3_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00224"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202413828","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202413828","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202413828","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T16:06:13Z","timestamp":1790784373000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202413828"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,16]]},"references-count":32,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2025,1,10]]}},"alternative-id":["10.1002\/anie.202413828"],"URL":"https:\/\/doi.org\/10.1002\/anie.202413828","archive":["Portico"],"relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2024-kq19w","asserted-by":"object"}]},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,16]]},"assertion":[{"value":"2024-07-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202413828"}}