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As such, the development of multifunctional materials for the selective capture and easy recognition of CS<jats:sub>2<\/jats:sub> is one of the crucial issues. Herein, we demonstrate completely selective CS<jats:sub>2<\/jats:sub> adsorption among trials involving H<jats:sub>2<\/jats:sub>O, alcohols, volatile organic compounds (including thiol derivatives), N<jats:sub>2<\/jats:sub>, H<jats:sub>2<\/jats:sub>, O<jats:sub>2<\/jats:sub>, CH<jats:sub>4<\/jats:sub>, CO, NO, and CO<jats:sub>2<\/jats:sub>. We also showcase its fine detection using remarkable luminescent response in a gold(I)\u2010based metal\u2212organic framework (MOF) of {Zn<jats:sup>II<\/jats:sup>(pz)[Au<jats:sup>I<\/jats:sup>(CN)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>} (pz=pyrazine; <jats:bold>1<\/jats:bold>) with a two\u2010fold interpenetration network. <jats:italic>Ex\u2005situ<\/jats:italic> single crystal X\u2010ray diffraction for <jats:bold>1<\/jats:bold> and CS<jats:sub>2<\/jats:sub>\u2010accommodated <jats:bold>1<\/jats:bold> suggested that the Au\u2009\u22c5\u22c5\u22c5\u2009Au atoms are not only luminescent centers but also act as interaction sites for CS<jats:sub>2<\/jats:sub> modulating the Au\u2009\u22c5\u22c5\u22c5\u2009Au contacts. These experiments revealed the specificity of CS<jats:sub>2<\/jats:sub> and how changes in the CS<jats:sub>2<\/jats:sub>\u2010induced structure. Based on the obtained structural transformation, <jats:bold>1<\/jats:bold> exhibited a sensitive detecting ability for CS<jats:sub>2<\/jats:sub> with an ultrafast response time of less than 10\u2005s. Moreover, <jats:italic>ex\u2005situ<\/jats:italic> time\u2010resolved photoluminescence analyses developed in this work implied that CS<jats:sub>2<\/jats:sub> varied the energetic relaxation at the excited states related to the luminescent efficiency of the resultant MOF system.<\/jats:p>","DOI":"10.1002\/anie.202413830","type":"journal-article","created":{"date-parts":[[2024,11,26]],"date-time":"2024-11-26T22:40:37Z","timestamp":1732660837000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Ultrafast Luminescence Detection with Selective Adsorption of Carbon Disulfide in a Gold(I) Metal\u2212Organic Framework"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3102-6222","authenticated-orcid":false,"given":"Haruka","family":"Yoshino","sequence":"first","affiliation":[{"name":"Institute for Materials Research Tohoku University  2-1-1 Katahira Aoba-ku Sendai 980-8577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masaki","family":"Saigo","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Kyushu University  Motooka 744 Nishi-ku Fukuoka 819-0395 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takumi","family":"Ehara","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Kyushu University  Motooka 744 Nishi-ku Fukuoka 819-0395 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6748-1337","authenticated-orcid":false,"given":"Kiyoshi","family":"Miyata","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Kyushu University  Motooka 744 Nishi-ku Fukuoka 819-0395 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1724-2009","authenticated-orcid":false,"given":"Ken","family":"Onda","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Kyushu University  Motooka 744 Nishi-ku Fukuoka 819-0395 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8866-4279","authenticated-orcid":false,"given":"Jenny","family":"Pirillo","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biotechnology School of Engineering Department of Materials Chemistry Graduate School of Engineering Nagoya University  Furo-cho Chikusa-ku Nagoya 464-8603 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4883-5085","authenticated-orcid":false,"given":"Yuh","family":"Hijikata","sequence":"additional","affiliation":[{"name":"Research Center for Net Zero Carbon Society Institute of Innovation for Future Society Nagoya University  Furo-cho Chikusa-ku Nagoya 464-8603 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6739-8119","authenticated-orcid":false,"given":"Shinya","family":"Takaishi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Tohoku University  Sendai Miyagi 980-8578 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2445-5099","authenticated-orcid":false,"given":"Wataru","family":"Kosaka","sequence":"additional","affiliation":[{"name":"Institute for Materials Research Tohoku University  2-1-1 Katahira Aoba-ku Sendai 980-8577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7904-5003","authenticated-orcid":false,"given":"Ken\u2010ichi","family":"Otake","sequence":"additional","affiliation":[{"name":"Institute for Integrated Cell-Material Sciences Institute for Advanced Study Kyoto University  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6956-9543","authenticated-orcid":false,"given":"Susumu","family":"Kitagawa","sequence":"additional","affiliation":[{"name":"Institute for Integrated Cell-Material Sciences Institute for Advanced Study Kyoto University  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9897-0782","authenticated-orcid":false,"given":"Hitoshi","family":"Miyasaka","sequence":"additional","affiliation":[{"name":"Institute for Materials Research Tohoku University  2-1-1 Katahira Aoba-ku Sendai 980-8577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,17]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie0492956"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2010.02.005"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp5058012"},{"key":"e_1_2_6_4_1","volume-title":"Ullmann's Encyclopedia of Industrial Chemistry","author":"Lay M. 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