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Here, we introduce 2\u2010bromomethyl\u20101,3\u2010dioxolane (BDOL) and methanol (MeOH) as electrolyte additive into aqueous ZnSO\n                    <jats:sub>4<\/jats:sub>\n                    electrolyte. In the as\u2010formulated electrolyte, BDOL with a strong electron\u2010withdrawing group (\u2212CH\n                    <jats:sub>2<\/jats:sub>\n                    Br) tends to pair with the H\n                    <jats:sub>2<\/jats:sub>\n                    O\u2212Zn\u2212MeOH complex, leading to the formation of organobromine\u2010partnered H\n                    <jats:sub>2<\/jats:sub>\n                    O\u2212Zn\u2212MeOH cluster ions. During the Zn electrodeposition process, the formed ZnO\u2010dominated by\u2010products induce the polymerization of BDOL monomers, which are previously adsorbed on the electrode. As a result, a uniform dual\u2010layer SEI with ZnO\u2010dominated outer layer and polyether\u2010dominated inner layer is built on the surface of Zn electrode. With such an in situ formed dual\u2010layer SEI, the Zn||Mg\n                    <jats:sub>0.9<\/jats:sub>\n                    Mn\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    \u2009\u22c5\u20092.7H\n                    <jats:sub>2<\/jats:sub>\n                    O pouch cell using a 10\u2010um Zn anode (corresponding to a low negative to positive areal capacity ratio of 3.56) successfully operated for 300\u2005cycles with a high capacity retention of 86\u2009%, promising a high practical energy density of &gt;120\u2005Wh\/kg (based on the total mass of Zn and Mg\n                    <jats:sub>0.9<\/jats:sub>\n                    Mn\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    \u2009\u22c5\u20092.7H\n                    <jats:sub>2<\/jats:sub>\n                    O).\n                  <\/jats:p>","DOI":"10.1002\/anie.202414562","type":"journal-article","created":{"date-parts":[[2024,10,10]],"date-time":"2024-10-10T08:10:53Z","timestamp":1728547853000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Thin Zinc Electrodes Stabilized with Organobromine\u2010Partnered H\n                    <sub>2<\/sub>\n                    O\u2212Zn\u2212MeOH Cluster Ions for Practical Zinc\u2010Metal Pouch Cells"],"prefix":"10.1002","volume":"64","author":[{"given":"Jie","family":"Ji","sequence":"first","affiliation":[{"name":"State Key Laboratory of Material Processing and Die &amp; Mold Technology School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoran","family":"Du","sequence":"additional","affiliation":[{"name":"Key Laboratory of Materials and Technologies for Advanced Batteries School 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