{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T16:57:57Z","timestamp":1790787477484,"version":"4.1.0"},"reference-count":136,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2024,11,6]],"date-time":"2024-11-06T00:00:00Z","timestamp":1730851200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,11,6]],"date-time":"2024-11-06T00:00:00Z","timestamp":1730851200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100002855","name":"Ministry of Science and Technology of the People's Republic of China","doi-asserted-by":"publisher","award":["2021YFA1200101"],"award-info":[{"award-number":["2021YFA1200101"]}],"id":[{"id":"10.13039\/501100002855","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002855","name":"Ministry of Science and Technology of the People's Republic of China","doi-asserted-by":"publisher","award":["2018YFA0702001"],"award-info":[{"award-number":["2018YFA0702001"]}],"id":[{"id":"10.13039\/501100002855","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22434005"],"award-info":[{"award-number":["22434005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21991132"],"award-info":[{"award-number":["21991132"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002731","name":"Anqing Normal University","doi-asserted-by":"publisher","award":["KJ202202ZD"],"award-info":[{"award-number":["KJ202202ZD"]}],"id":[{"id":"10.13039\/501100002731","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,1,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Silver nanoparticles (AgNPs) have superior plasmonic properties surpassing other metals. However, a long\u2010standing difficulty in valence\/density\u2010tunable DNA grafting of AgNPs disfavors their use in DNA\u2010directed nanoplasmonics. Herein a close\u2010to\u2010ideal surface protection of pristine AgNPs against various notorious stability issues of Ag is achieved based on multidentate weak nucleobase bindings of non\u2010programming FSDNA (fish sperm DNA). This further allows grafting of thiolated DNA with tunable valence\/density on AgNPs. The end\u2010on format of the thiolated DNA grafts and the very thin FSDNA layer benefit DNA hybridization and plasmon coupling, respectively. Significantly promoted optical coupling and Raman enhancing are achieved. The compatibility of FSDNA\u2010capped AgNPs with Au enables DNA\u2010bonded symmetry\u2010broken Au\u2212Ag heterodimers with strong near\u2010field coupling and an easily seen Fano\u2010induced feature. Our work provides a treasured freedom of using AgNPs in DNA\u2010programmed, better\u2010behaving plasmonic devices.<\/jats:p>","DOI":"10.1002\/anie.202414752","type":"journal-article","created":{"date-parts":[[2024,9,25]],"date-time":"2024-09-25T07:45:23Z","timestamp":1727250323000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Multivalent Weak Protections Ultimately Enable Customizable DNA Grafting on Pristine Ag Colloids for Nanoplasmonics"],"prefix":"10.1002","volume":"64","author":[{"given":"Lei","family":"Song","sequence":"first","affiliation":[{"name":"Center for Bioanalytical Chemistry, Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"College of Resources and Environment Anqing Normal University  Anqing Anhui 246011 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojun","family":"Song","sequence":"additional","affiliation":[{"name":"Center for Bioanalytical Chemistry, Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanjuan","family":"Li","sequence":"additional","affiliation":[{"name":"Center for Bioanalytical Chemistry, Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Hao","sequence":"additional","affiliation":[{"name":"Center for Bioanalytical Chemistry, Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Wang","sequence":"additional","affiliation":[{"name":"Center for Bioanalytical Chemistry, Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0811-5147","authenticated-orcid":false,"given":"Zhaoxiang","family":"Deng","sequence":"additional","affiliation":[{"name":"Center for Bioanalytical Chemistry, Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,6]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature01406"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1260901"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2017.68"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1369-7021(09)70157-9"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar400305g"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja505101a"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/cnma.201700222"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00225"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0549-3"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00211"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp0516846"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1077229"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl504126u"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja503509k"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.5b01337"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12143"},{"key":"e_1_2_7_20_1","unstructured":"\u00a0"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527618156"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100313v"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202005400"},{"key":"e_1_2_7_24_1","unstructured":"\u00a0"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503208"},{"key":"e_1_2_7_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200503208"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC52445K"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b01196"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja511333q"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4571"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03966"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201712749"},{"key":"e_1_2_7_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201712749"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202107875"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3647"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2013.209"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000330"},{"key":"e_1_2_7_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201000330"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9101198"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.2c00656"},{"key":"e_1_2_7_38_1","unstructured":"\u00a0"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp037644o"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3151"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.97.206806"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp209466k"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8006337"},{"key":"e_1_2_7_44_1","unstructured":"\u00a0"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310097"},{"key":"e_1_2_7_45_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310097"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1032"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b07966"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c04058"},{"key":"e_1_2_7_49_1","unstructured":"\u00a0"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja046779k"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/b417683a"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc32338a"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc35008d"},{"key":"e_1_2_7_54_1","unstructured":"\u00a0"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.8b02325"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.7b10381"},{"key":"e_1_2_7_57_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC07729F"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8MH01126E"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b02653"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b09546"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202202458"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja302518n"},{"key":"e_1_2_7_63_1","unstructured":"\u00a0"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00733"},{"key":"e_1_2_7_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/es2038596"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp711616v"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl101380f"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1039\/b911069k"},{"key":"e_1_2_7_69_1","unstructured":"\u00a0"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja050432f"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11434-014-0122-z"},{"key":"e_1_2_7_72_2","doi-asserted-by":"publisher","DOI":"10.1039\/b800109j"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl071108g"},{"key":"e_1_2_7_74_1","unstructured":"\u00a0"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2an35167f"},{"key":"e_1_2_7_76_2","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-012-0244-z"},{"key":"e_1_2_7_77_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja011342n"},{"key":"e_1_2_7_78_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC01171A"},{"key":"e_1_2_7_79_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b14976"},{"key":"e_1_2_7_80_1","unstructured":"\u00a0"},{"key":"e_1_2_7_81_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00363"},{"key":"e_1_2_7_82_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00011E"},{"key":"e_1_2_7_83_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201505049"},{"key":"e_1_2_7_84_1","unstructured":"\u00a0"},{"key":"e_1_2_7_85_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfb.2016.09.022"},{"key":"e_1_2_7_86_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.0c02122"},{"key":"e_1_2_7_87_2","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201701223"},{"key":"e_1_2_7_88_2","first-page":"69","volume":"1","author":"Eidelshtein G.","year":"2013","journal-title":"SAME"},{"key":"e_1_2_7_89_1","unstructured":"\u00a0"},{"key":"e_1_2_7_90_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja035756n"},{"key":"e_1_2_7_91_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2008.02.015"},{"key":"e_1_2_7_92_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.6b01192"},{"key":"e_1_2_7_93_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19981102)37:20<2754::AID-ANIE2754>3.0.CO;2-3"},{"key":"e_1_2_7_93_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19981016)110:20<2908::AID-ANGE2908>3.0.CO;2-2"},{"key":"e_1_2_7_94_1","unstructured":"\u00a0"},{"key":"e_1_2_7_95_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC01407K"},{"key":"e_1_2_7_96_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00463"},{"key":"e_1_2_7_97_1","unstructured":"\u00a0"},{"key":"e_1_2_7_98_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2015.10.019"},{"key":"e_1_2_7_99_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl025888z"},{"key":"e_1_2_7_100_1","unstructured":"\u00a0"},{"key":"e_1_2_7_101_2","doi-asserted-by":"publisher","DOI":"10.1038\/35020524"},{"key":"e_1_2_7_102_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00580"},{"key":"e_1_2_7_103_1","unstructured":"\u00a0"},{"key":"e_1_2_7_104_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature11653"},{"key":"e_1_2_7_105_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200061k"},{"key":"e_1_2_7_106_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abj9752"},{"key":"e_1_2_7_107_2","doi-asserted-by":"publisher","DOI":"10.1364\/OE.14.009988"},{"key":"e_1_2_7_108_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2596"},{"key":"e_1_2_7_109_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaq0591"},{"key":"e_1_2_7_110_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl049681c"},{"key":"e_1_2_7_111_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.020.202000290"},{"key":"e_1_2_7_112_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn800466c"},{"key":"e_1_2_7_113_1","doi-asserted-by":"publisher","DOI":"10.1021\/la00013a004"},{"key":"e_1_2_7_114_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac302073f"},{"key":"e_1_2_7_115_1","unstructured":"\u00a0"},{"key":"e_1_2_7_116_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp0257449"},{"key":"e_1_2_7_117_2","volume-title":"Vibrational Spectra and Structure: Vibrational Intensities","author":"Galabov B. S.","year":"1996"},{"key":"e_1_2_7_118_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1701032"},{"key":"e_1_2_7_119_1","unstructured":"\u00a0"},{"key":"e_1_2_7_120_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.65.115418"},{"key":"e_1_2_7_121_2","doi-asserted-by":"publisher","DOI":"10.1103\/RevModPhys.82.209"},{"key":"e_1_2_7_122_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2011.09.009"},{"key":"e_1_2_7_123_1","unstructured":"\u00a0"},{"key":"e_1_2_7_124_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2006.03.042"},{"key":"e_1_2_7_125_2","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.21"},{"key":"e_1_2_7_126_1","unstructured":"\u00a0"},{"key":"e_1_2_7_127_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.101.197401"},{"key":"e_1_2_7_128_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp200495x"},{"key":"e_1_2_7_129_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp105522b"},{"key":"e_1_2_7_130_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3628346"},{"key":"e_1_2_7_131_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b02680"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202414752","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202414752","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202414752","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T16:01:16Z","timestamp":1790784076000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202414752"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,6]]},"references-count":136,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2025,1,10]]}},"alternative-id":["10.1002\/anie.202414752"],"URL":"https:\/\/doi.org\/10.1002\/anie.202414752","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,6]]},"assertion":[{"value":"2024-08-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202414752"}}