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Rare earth elements play a unique role in band hybridization due to their deep orbitals and strong localization of 4\u2009\n                    <jats:italic>f<\/jats:italic>\n                    electrons. Herein, we anchor single Ce atoms onto CoO, constructing a highly active and stable catalyst with\n                    <jats:italic>d<\/jats:italic>\n                    \u2010\n                    <jats:italic>f<\/jats:italic>\n                    a dual\u2010band redox center. It is discovered that the itinerant behavior of 4\u2009\n                    <jats:italic>f<\/jats:italic>\n                    electrons introduces an enhanced spin\u2010orbit coupling effect, which facilitates ideal \u03c3\/\u03c0 bonding and flexible adsorption between the Ce\/Co active sites and *O. Simultaneously, the injection of localized Ce 4\u2009\n                    <jats:italic>f<\/jats:italic>\n                    electrons strengthens the orbital bonding capacity of Co\u2212O, effectively inhibits the dissolution of Co sites and improves the structural stability of the cathode material. Bracingly, the Ce\n                    <jats:sub>1<\/jats:sub>\n                    \/CoO\u2010based LOB exhibits an ultra\u2010low charge\u2013discharge polarization (0.46\u2005V) and stable cyclic performance (1088\u2005hours). This work breaks through the traditional limitations in catalyst activity and stability, providing new strategies and theoretical insights for developing high\u2010performance LOBs powered by rare\u2010earth elements.\n                  <\/jats:p>","DOI":"10.1002\/anie.202414893","type":"journal-article","created":{"date-parts":[[2024,9,24]],"date-time":"2024-09-24T09:05:24Z","timestamp":1727168724000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["Harnessing 4\n                    <i>f<\/i>\n                    Electron Itinerancy for Integrated Dual\u2010Band Redox Systems Boosts Lithium\u2010Oxygen Batteries Electrocatalysis"],"prefix":"10.1002","volume":"64","author":[{"given":"Mengyao","family":"Huang","sequence":"first","affiliation":[{"name":"College of Chemistry Zhengzhou University  Zhengzhou 450001 P.R. 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