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Porous organic molecular frameworks constructed via noncovalent \u03c0\u2010interactions are emerging as novel adsorbents with vast potential in gas adsorption and molecular separation. Herein, we report a permanent two\u2010dimensional porous structure, namely\n                    <jats:bold>TDTBA\u20101<\/jats:bold>\n                    , which consists of two different kinds of pores through \u03c0\u2010stacking of a single organic molecule with highly\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>d<\/jats:sub>\n                    symmetry. Activated\n                    <jats:bold>TDTBA\u20101<\/jats:bold>\n                    exhibits excellent hydrophobicity, thermal stability, recoverability and high selectivity for ethanol over water, and benzene over methanol. Therefore, activated\n                    <jats:bold>TDTBA\u20101<\/jats:bold>\n                    can be used as an efficient stationary phase for the separation of ethanol\/water and benzene\/methanol azeotropes by high\u2010resolution gas chromatography.\n                  <\/jats:p>","DOI":"10.1002\/anie.202415346","type":"journal-article","created":{"date-parts":[[2024,11,14]],"date-time":"2024-11-14T23:19:51Z","timestamp":1731626391000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["A Noncovalent \u03c0\u2010Stacked Dual\u2010Pore Molecular Crystal for Ethanol\/Water and Benzene\/Methanol Azeotrope Separation"],"prefix":"10.1002","volume":"64","author":[{"given":"Xiang","family":"Meng","sequence":"first","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuixiang","family":"Zou","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiawei","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou 350108"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Zhang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2610-285X","authenticated-orcid":false,"given":"Mingyan","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou 350108"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,20]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0604600103"},{"key":"e_1_2_3_2_1","unstructured":"\u00a0"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-020-3258-y"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216710"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303374"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2009.04.020"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13480"},{"key":"e_1_2_3_8_1","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc38260e"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT01147D"},{"key":"e_1_2_3_11_1","unstructured":"\u00a0"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2020.124213"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300262"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/532435a"},{"key":"e_1_2_3_15_1","unstructured":"\u00a0"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108326"},{"key":"e_1_2_3_17_2","author":"Li J.-H.","year":"2024","journal-title":"Angew. 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