{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T23:07:47Z","timestamp":1788217667025,"version":"build-2803163510"},"reference-count":85,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2025,9,19]],"date-time":"2025-09-19T00:00:00Z","timestamp":1758240000000},"content-version":"am","delay-in-days":323,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2024,10,31]],"date-time":"2024-10-31T00:00:00Z","timestamp":1730332800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,10,31]],"date-time":"2024-10-31T00:00:00Z","timestamp":1730332800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0010596"],"award-info":[{"award-number":["DE-SC0010596"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["2117040"],"award-info":[{"award-number":["2117040"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,1,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Compared to exploratory development of new structure types, pushing the limits of isoreticular synthesis on a high\u2010performance MOF platform may have higher probability of achieving targeted properties. Multi\u2010modular MOF platforms could offer even more opportunities by expanding the scope of isoreticular chemistry. However, navigating isoreticular chemistry towards best properties on a multi\u2010modular platform is challenging due to multiple interconnected pathways. Here on the multi\u2010modular pacs (partitioned acs) platform, we demonstrate accessibility to a new regime of pore geometry using two independently adjustable modules (framework\u2010forming module 1 and pore\u2010partitioning module 2). A series of new pacs materials have been made. Benzene\/cyclohexane selectivity is tuned, progressively, from 4.5 to 15.6 to 195.4 and to 482.5 by pushing the boundary of the pacs platform towards the smallest modules known so far. The exceptional stability of these materials in retaining both porosity and single crystallinity enables single\u2010crystal diffraction studies of different crystal forms (as\u2010synthesized, activated, guest\u2010loaded) that help reveal the mechanistic aspects of adsorption in pacs materials.<\/jats:p>","DOI":"10.1002\/anie.202415576","type":"journal-article","created":{"date-parts":[[2024,9,19]],"date-time":"2024-09-19T14:25:07Z","timestamp":1726755907000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Multi\u2010Stage Optimization of Pore Size and Shape in Pore\u2010Space\u2010Partitioned Metal\u2013Organic Frameworks for Highly Selective and Sensitive Benzene Capture"],"prefix":"10.1002","volume":"64","author":[{"given":"Yichong","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Chemistry University of California Riverside 900 University Ave  Riverside CA-92521 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California Riverside 900 University Ave  Riverside CA-92521 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samuel","family":"Alston","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California Riverside 900 University Ave  Riverside CA-92521 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuchen","family":"Xiao","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California Riverside 900 University Ave  Riverside CA-92521 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pooja","family":"Ajayan","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California Riverside 900 University Ave  Riverside CA-92521 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianhui","family":"Bu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry California State University  Long Beach 1250 Bellflower Blvd Long Beach CA-90840 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3684-577X","authenticated-orcid":false,"given":"Pingyun","family":"Feng","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California Riverside 900 University Ave  Riverside CA-92521 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,31]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.10.012"},{"key":"e_1_2_3_2_1","unstructured":"\u00a0"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz4304"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja512311a"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1067208"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-0225-x"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2017.12.026"},{"key":"e_1_2_3_8_1","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03916C"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3MH00541K"},{"key":"e_1_2_3_11_1","unstructured":"\u00a0"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0753952"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature02294"},{"key":"e_1_2_3_14_1","unstructured":"\u00a0"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja045123o"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8057953"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja1065009"},{"key":"e_1_2_3_18_1","unstructured":"\u00a0"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja512137t"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00526"},{"key":"e_1_2_3_21_1","unstructured":"\u00a0"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07901"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms13645"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901343"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07277"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116064"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300721"},{"key":"e_1_2_3_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008696"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b12924"},{"key":"e_1_2_3_30_2","author":"Hong A. N.","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"e_1_2_3_31_1","unstructured":"\u00a0"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09349"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c05980"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202205119"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03130"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202303540"},{"key":"e_1_2_3_37_1","unstructured":"\u00a0"},{"key":"e_1_2_3_38_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01237-x"},{"key":"e_1_2_3_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202109964"},{"key":"e_1_2_3_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2023.02.002"},{"key":"e_1_2_3_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08322"},{"key":"e_1_2_3_42_1","unstructured":"Deposition numbers 2344738 (forCoV-BDC-TPA) 2344739 (forCoV-FA-TPA) 2344740 (forCoV-BDC-TPT-act) 2344741 (forCoV-BDC-TPA-act) 2344742 (forCoV-BDC-TPT-Bz) 2344743 (forCoV-BDC-TPA-Bz) 2344744 (forCoV-FA-TPA-Bz) 2344745 (forCoV-BDC-TPT-Ch) 2344746 (forCoV-BDC-TPA-Ch) 2344747 (forCoV-FA-TPA-Ch) 2344748 (forCoV-BDC-TPT-Mix) 2344749 (forCoV-BDC-TPA-Mix) 2344750 (forCoV-FA-TPA-Mix) 2344752 (forInNi-BCP-TPA) 2344753 (forInNi-BCP-TPA-Bz) 2344754 (forInNi-BCP-TPA-Mix) 2344755 (forCoV-BCP-TPT-act) 2344756 (forCoV-BCP-TPT-Bz) 2344757 (forCoV-BCP-TPT-Ch) 2344758 (forCoV-BCP-TPT-Mix) 2344759 (forCoIn-FA-TPA) 2345014 (forCoV-FA-TPA-act) 2345015 (forInNi-BCP-TPA-act) and 2345017 (forInNi-BCP-TPA-Ch) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structuresservice."},{"key":"e_1_2_3_43_1","unstructured":"\u00a0"},{"key":"e_1_2_3_44_2","doi-asserted-by":"publisher","DOI":"10.1038\/41937"},{"key":"e_1_2_3_45_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.278.5346.2080"},{"key":"e_1_2_3_46_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature02159"},{"key":"e_1_2_3_47_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1078663"},{"key":"e_1_2_3_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013988"},{"key":"e_1_2_3_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201908275"},{"key":"e_1_2_3_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00232"},{"key":"e_1_2_3_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02030"},{"key":"e_1_2_3_52_1","unstructured":"\u00a0"},{"key":"e_1_2_3_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690110125"},{"key":"e_1_2_3_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01784"},{"key":"e_1_2_3_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202117807"},{"key":"e_1_2_3_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10620"},{"key":"e_1_2_3_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101907"},{"key":"e_1_2_3_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c02101"},{"key":"e_1_2_3_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202110820"},{"key":"e_1_2_3_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015861"},{"key":"e_1_2_3_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja073505z"},{"key":"e_1_2_3_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja800550a"},{"key":"e_1_2_3_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/b901574d"},{"key":"e_1_2_3_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic900621c"},{"key":"e_1_2_3_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm101410h"},{"key":"e_1_2_3_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201000218"},{"key":"e_1_2_3_67_2","volume":"21","author":"Ren G.","year":"2011","journal-title":"J. Mater. Chem."},{"key":"e_1_2_3_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201003734"},{"key":"e_1_2_3_69_2","volume":"2","author":"Ren C.-X.","year":"2014","journal-title":"J. Mater. Chem. A"},{"key":"e_1_2_3_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406233"},{"key":"e_1_2_3_71_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC03015G"},{"key":"e_1_2_3_72_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201600705"},{"key":"e_1_2_3_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b06339"},{"key":"e_1_2_3_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b13639"},{"key":"e_1_2_3_75_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC03227A"},{"key":"e_1_2_3_76_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI00181C"},{"key":"e_1_2_3_77_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT01126A"},{"key":"e_1_2_3_78_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b13548"},{"key":"e_1_2_3_79_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b00346"},{"key":"e_1_2_3_80_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201003314"},{"key":"e_1_2_3_81_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC03204G"},{"key":"e_1_2_3_82_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC06128H"},{"key":"e_1_2_3_83_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016225"},{"key":"e_1_2_3_84_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000323"},{"key":"e_1_2_3_85_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03850"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202415576","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202415576","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/anie.202415576","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202415576","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T07:12:32Z","timestamp":1781161952000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202415576"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,10,31]]},"references-count":85,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2025,1,15]]}},"alternative-id":["10.1002\/anie.202415576"],"URL":"https:\/\/doi.org\/10.1002\/anie.202415576","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,10,31]]},"assertion":[{"value":"2024-08-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-10-31","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202415576"}}