{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T07:20:08Z","timestamp":1792826408076,"version":"4.5.0"},"reference-count":69,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2024,11,6]],"date-time":"2024-11-06T00:00:00Z","timestamp":1730851200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,11,6]],"date-time":"2024-11-06T00:00:00Z","timestamp":1730851200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52102302"],"award-info":[{"award-number":["52102302"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["5237011592"],"award-info":[{"award-number":["5237011592"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22409161"],"award-info":[{"award-number":["22409161"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011436","name":"State Key Laboratory of Electrical Insulation and Power Equipment","doi-asserted-by":"publisher","award":["EIPE23313"],"award-info":[{"award-number":["EIPE23313"]}],"id":[{"id":"10.13039\/501100011436","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,1,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    High\u2010voltage sodium metal batteries (SMBs) present a viable pathway towards high\u2010energy\u2010density sodium\u2010based batteries due to the competitive cost advantage and abundant supply of sodium resources. However, they still suffer from severe capacity decay induced by the notorious decomposition of the electrolyte under high voltage and unstable cathode\/electrolyte interphase (CEI). In addition, the high reactivity of Na metal and flammable electrolytes push SMBs to their safety limits. Herein, a special dual\u2010anion aggregated Na\n                    <jats:sup>+<\/jats:sup>\n                    solvation structure is designed in a nonflammable trimethyl phosphate\u2010based localized high\u2010concentration electrolyte, and a gradient CEI enriched with phosphorus and boron compounds is formed on the cathode. This thin and stable interphase effectively suppresses the parasitic reaction, improves the interfacial stability of the cathode, and facilitates Na\n                    <jats:sup>+<\/jats:sup>\n                    transport through the interface by the synergistic effect of multi\u2010components, thus optimizing the cycling stability and safety of SMBs. The Na\n                    <jats:sub>0.95<\/jats:sub>\n                    Ni\n                    <jats:sub>0.4<\/jats:sub>\n                    Fe\n                    <jats:sub>0.15<\/jats:sub>\n                    Mn\n                    <jats:sub>0.3<\/jats:sub>\n                    Ti\n                    <jats:sub>0.15<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    \/\/Na batteries employing such electrolyte provide a discharge capacity of 167.5\u2005mAh\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and high retention in the capacity of 85.2\u2009% after 800\u2005cycles at 1\u2005C. This approach offers a general strategy for the design of flame\u2010retardant high\u2010voltage electrolytes and the practical application of SMBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202415644","type":"journal-article","created":{"date-parts":[[2024,10,4]],"date-time":"2024-10-04T03:04:05Z","timestamp":1728011045000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":68,"title":["Dual\u2010Anionic Coordination Manipulation Induces Phosphorus and Boron\u2010Rich Gradient Interphase Towards Stable and Safe Sodium Metal Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Yi\u2010Hu","family":"Feng","sequence":"first","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengting","family":"Liu","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenli","family":"Qi","sequence":"additional","affiliation":[{"name":"School of Optical and Electronic Information-Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology  Wuhan Hubei 430074 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoliang","family":"Liu","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Liu","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology  Wuhan Hubei 430070 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongwei","family":"Tang","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Zhu","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuai","family":"Sun","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan\u2010Meng","family":"Li","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tian\u2010Ling","family":"Chen","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing","family":"Xiao","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Ji","sequence":"additional","affiliation":[{"name":"School of Optical and Electronic Information-Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology  Wuhan Hubei 430074 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ya","family":"You","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology  Wuhan Hubei 430070 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9882-5059","authenticated-orcid":false,"given":"Peng\u2010Fei","family":"Wang","sequence":"additional","affiliation":[{"name":"Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical Engineering Xi'an Jiaotong University  Xi'an Shaanxi 710049 P.\u2005R. China"},{"name":"Jiangsu Jufeng New Energy Technology Co. Ltd.  Changzhou Jiangsu 213166 P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,6]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c03469"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2021.03.004"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202315437"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.06.012"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40242-023-3196-9"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40242-023-3107-0"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40242-023-3126-x"},{"key":"e_1_2_7_9_1","unstructured":"\u00a0"},{"key":"e_1_2_7_10_2","author":"Li J.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE03477A"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201903891"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202311810"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.07.012"},{"key":"e_1_2_7_15_1","unstructured":"\u00a0"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310051"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202315007"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202002737"},{"key":"e_1_2_7_19_1","unstructured":"\u00a0"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c02811"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112550"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202200410"},{"key":"e_1_2_7_23_1","unstructured":"\u00a0"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202400169"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202206340"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01296-0"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmst.2021.11.034"},{"key":"e_1_2_7_28_1","unstructured":"\u00a0"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2022.01.012"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300443"},{"key":"e_1_2_7_31_1","unstructured":"\u00a0"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102403"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202300629"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913174"},{"key":"e_1_2_7_35_1","unstructured":"\u00a0"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201802176"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA08404J"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0567-z"},{"key":"e_1_2_7_39_1","unstructured":"\u00a0"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC00994E"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.05.045"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08733"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c02903"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112382"},{"key":"e_1_2_7_46_1","unstructured":"\u00a0"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA03436B"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abm4606"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40242-023-3099-9"},{"key":"e_1_2_7_50_1","author":"Feng Y.-H.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216189"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36647-1"},{"key":"e_1_2_7_53_1","unstructured":"\u00a0"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2316914121"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01443-0"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c02514"},{"key":"e_1_2_7_57_1","unstructured":"\u00a0"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE03632B"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313447"},{"key":"e_1_2_7_60_1","unstructured":"\u00a0"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09241"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.08.004"},{"key":"e_1_2_7_63_2","volume":"2022","author":"Zheng X.","year":"2022","journal-title":"Research"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-23368-6"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307220"},{"key":"e_1_2_7_66_1","unstructured":"\u00a0"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b12030"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b00436"},{"key":"e_1_2_7_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5b05283"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202415644","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202415644","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202415644","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T07:22:01Z","timestamp":1781162521000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202415644"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,6]]},"references-count":69,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2025,1,15]]}},"alternative-id":["10.1002\/anie.202415644"],"URL":"https:\/\/doi.org\/10.1002\/anie.202415644","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,6]]},"assertion":[{"value":"2024-08-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202415644"}}