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The success of the reaction relies on the temporary coordination between in situ generated dihaloboranes and amines under mild reaction conditions. In addition, cyclobutanes with varying substitution patterns have been prepared using\n                    <jats:italic>N<\/jats:italic>\n                    \u2010heterocycles as directing group. Manipulation of the C\u2212B bond allows for the synthesis of a diverse class of cyclobutanes from simple precursors. Moreover, these reactions lead to the synthesis of complex amines and heteroaromatic compounds, which have significant utility in medicinal chemistry. Finally, a dearomative [4+2]\u2010cycloaddition of naphthalenes using a boron\u2010enabled temporary tethering strategy has also been uncovered to synthesize complex 3\u2010dimensional borylated building blocks.\n                  <\/jats:p>","DOI":"10.1002\/anie.202416215","type":"journal-article","created":{"date-parts":[[2024,11,7]],"date-time":"2024-11-07T09:06:12Z","timestamp":1730970372000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Boron Enabled Directed [2+2]\u2010 and Dearomative [4+2]\u2010Cycloadditions Initiated by Energy Transfer"],"prefix":"10.1002","volume":"64","author":[{"given":"Souvik","family":"Adak","sequence":"first","affiliation":[{"name":"Department of Chemistry Indiana University  800 E. Kirkwood Ave. Bloomington IN 47401 US"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Partha Sarathi","family":"Hazra","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 E. Kirkwood Ave. Bloomington IN 47401 US"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carter B.","family":"Fox","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 E. Kirkwood Ave. Bloomington IN 47401 US"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4993-0917","authenticated-orcid":false,"given":"M. Kevin","family":"Brown","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 E. 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