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Herein, we fabricate a hydrogen\u2010bonded organic framework (HOF) enriched with zincophilic sites as a multifunctional layer to regulate Zn anodes with controlled spatial ion flux and stable interfacial chemistry (MA\u2010BTA@Zn). The framework with abundant H\u2010bonds helps capture H\n                    <jats:sub>2<\/jats:sub>\n                    O and remove the solvated shells on [Zn(H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>2+<\/jats:sup>\n                    , leading to suppressed side reactions. The HOF layer also helps form electrolyte\u2010philic surfaces and expose Zn (002) crystal planes which benefit for rapid conduction and uniform deposition of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , and weakened sides reactions. Additionally, the electrochemically active zincophilic sites (C=O, \u2212NH\n                    <jats:sub>2<\/jats:sub>\n                    and triazine groups) favor the targeted guidance and penetration of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    and provide advantageous sites for uniform Zn deposition. High Young's modulus of the HOF layer further contributes to a high interfacial flexibility and stability against Zn plating\u2010associated stress. The MA\u2010BTA@Zn symmetric cells thereby obtain a substantially extended battery life over 1000\u2005h at 4\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The MA\u2010BTA@Zn||Cu half\u2010cell demonstrates a highly reversible Zn stripping\/plating process over 1500\u2005cycles with impressive average Coulombic efficiency (CE) of 99.5\u2009% at 10\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/anie.202416271","type":"journal-article","created":{"date-parts":[[2024,9,11]],"date-time":"2024-09-11T06:23:47Z","timestamp":1726035827000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":57,"title":["Zincophilic Sites Enriched Hydrogen\u2010Bonded Organic Framework as Multifunctional Regulating Interfacial Layers for Stable Zinc Metal Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Jie","family":"Ding","sequence":"first","affiliation":[{"name":"School of Environmental and Chemical Engineering Shanghai University  99 Shangda Road Shanghai P. R. 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