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For scalable applications, near\u2010unity methanol selectivity is highly desirable to reduce the energy and cost endowed by low\u2010value byproducts and complex separation processes, but so far has not been achieved. Here we demonstrate a molecule\/nanocarbon hybrid catalyst composed of carbon nanotube\u2010supported molecularly dispersed cobalt phthalocyanine (CoPc\/CNT), which synergistically integrates high photothermal conversion capability for affording an optimal reaction temperature with homogeneous and intrinsically\u2010efficient active sites, to achieve a catalytic activity of 2.4\u2005mmol\u2009g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    and selectivity of ~99\u2009% in direct photothermal CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol reaction. Both theoretical calculations and operando characterizations consistently confirm that the unique electronic structure of CoPc and appropriate reaction temperature cooperatively enable a thermodynamic favorable reaction pathway for highly selective methanol production. This work represents an important milestone towards the development of advanced photothermal catalysts for scalable and cost\u2010effective CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202416376","type":"journal-article","created":{"date-parts":[[2024,11,5]],"date-time":"2024-11-05T06:25:13Z","timestamp":1730787913000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Near\u2010Unity Photothermal CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol Based on a Molecule\/Nanocarbon Hybrid Catalyst"],"prefix":"10.1002","volume":"64","author":[{"given":"Siyun","family":"Ren","sequence":"first","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junnan","family":"Han","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengwei","family":"Yang","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Liang","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shijia","family":"Feng","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xing","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Xu","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"},{"name":"School of Microelectronics and School of Integrated Circuits Nantong University  Nantong 226019 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2871-4369","authenticated-orcid":false,"given":"Jia","family":"Zhu","sequence":"additional","affiliation":[{"name":"National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, College of Engineering and Applied Sciences Nanjing University  Nanjing, Jiangsu 210093 P. R. China"},{"name":"School of Sustainable Energy and Resources Nanjing University  Suzhou 215163 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,21]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-14817-9"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29222-7"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120994"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01331E"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00584-3"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2021.04.059"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.04.024"},{"key":"e_1_2_3_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.01.017"},{"key":"e_1_2_3_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.01.018"},{"key":"e_1_2_3_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2023.100507"},{"key":"e_1_2_3_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.08.016"},{"key":"e_1_2_3_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10524-2"},{"key":"e_1_2_3_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201802081"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.03.007"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.01.004"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.03.003"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19997-y"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2011.08.010"},{"key":"e_1_2_3_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE01124J"},{"key":"e_1_2_3_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00614A"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42247-022-00425-4"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2021.10.005"},{"key":"e_1_2_3_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00289-y"},{"key":"e_1_2_3_24_1","author":"Zhu H.","year":"2024","journal-title":"Small"},{"key":"e_1_2_3_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CC02851A"},{"key":"e_1_2_3_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1760-8"},{"key":"e_1_2_3_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41524-024-01325-3"},{"key":"e_1_2_3_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/j150609a003"},{"key":"e_1_2_3_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar50117a003"},{"key":"e_1_2_3_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02761"},{"key":"e_1_2_3_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.07.009"},{"key":"e_1_2_3_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0667-9"},{"key":"e_1_2_3_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-024-01190-9"},{"key":"e_1_2_3_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c01109"},{"key":"e_1_2_3_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c04659"},{"key":"e_1_2_3_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905869"},{"key":"e_1_2_3_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms14675"},{"key":"e_1_2_3_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201808593"},{"key":"e_1_2_3_39_1","volume":"58","author":"Cao S.","year":"2023","journal-title":"J. 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