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Pre\u2010 and post\u2010reaction surface and bulk characterization, along with density functional theory (DFT) computations, explicate the dual role of the metal\u2010support interface of Cu\/ZnZrO\n                    <jats:sub>x<\/jats:sub>\n                    in activating both CH\n                    <jats:sub>3<\/jats:sub>\n                    OH and DMT and facilitating a lower free\u2010energy pathway for both CH\n                    <jats:sub>3<\/jats:sub>\n                    OH dehydrogenation and DMT hydrogenolysis, compared to Cu supported on a redox\u2010neutral SiO\n                    <jats:sub>2<\/jats:sub>\n                    support. Loading studies and thermodynamic calculations showed that, under reaction conditions, CH\n                    <jats:sub>3<\/jats:sub>\n                    OH in the gas phase, rather than in the liquid phase, is critical for CTH of DMT. Interestingly, the Cu\/ZnZrO\n                    <jats:sub>x<\/jats:sub>\n                    catalyst was also effective for the methanolysis and hydrogenolysis of C\u2212C bonds (compared to C\u2212O bonds for PET) of waste polycarbonate (PC), largely forming xylenol (~38\u2009%) and methyl isopropyl anisole (~42\u2009%) demonstrating the versatility of this approach toward valorizing a wide range of condensation polymers.\n                  <\/jats:p>","DOI":"10.1002\/anie.202416384","type":"journal-article","created":{"date-parts":[[2024,10,7]],"date-time":"2024-10-07T09:14:54Z","timestamp":1728292494000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["Tandem Methanolysis and Catalytic Transfer Hydrogenolysis of Polyethylene Terephthalate to p\u2010Xylene Over Cu\/ZnZrO\n                    <sub>x<\/sub>\n                    Catalysts"],"prefix":"10.1002","volume":"64","author":[{"given":"Ryan","family":"Helmer","sequence":"first","affiliation":[{"name":"Artie McFerrin Department of Chemical Engineering Texas A&amp;M University  100 Spence Street 77843 College Station TX USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siddhesh S.","family":"Borkar","sequence":"additional","affiliation":[{"name":"Artie McFerrin Department of Chemical Engineering Texas A&amp;M University  100 Spence Street 77843 College Station TX USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aojie","family":"Li","sequence":"additional","affiliation":[{"name":"Chemical and Biomolecular Engineering Lehigh University  HST Building, L136\u2005124 E. Morton Street 18015 Bethlehem PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fatima","family":"Mahnaz","sequence":"additional","affiliation":[{"name":"Artie McFerrin Department of Chemical Engineering Texas A&amp;M University  100 Spence Street 77843 College Station TX USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jenna","family":"Vito","sequence":"additional","affiliation":[{"name":"Artie McFerrin Department of Chemical Engineering Texas A&amp;M University  100 Spence Street 77843 College Station TX USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michelle","family":"Bishop","sequence":"additional","affiliation":[{"name":"Artie McFerrin Department of Chemical Engineering Texas A&amp;M University  100 Spence Street 77843 College Station TX USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ashfaq","family":"Iftakher","sequence":"additional","affiliation":[{"name":"Artie McFerrin Department of Chemical Engineering Texas A&amp;M University  100 Spence Street 77843 College Station TX USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M. M. Faruque","family":"Hasan","sequence":"additional","affiliation":[{"name":"Artie McFerrin Department of Chemical Engineering Texas A&amp;M University  100 Spence Street 77843 College Station TX USA"},{"name":"Texas A&amp;M Energy Institute  617 Research Parkway 77843-3372 College Station TX USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Srinivas","family":"Rangarajan","sequence":"additional","affiliation":[{"name":"Chemical and Biomolecular Engineering Lehigh University  HST Building, L136\u2005124 E. 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