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However, waste\u2010derived phosphorus compounds, primarily as chemically inert phosphoric acid or its salts, present a challenge to their direct conversion into high\u2010value chemicals. We aimed to develop an innovative technology that utilizes the large quantities of sewage waste, bypasses the use of white phosphorus, and enables esterification of phosphoric acid to produce widely applicable phosphate triesters. Tetraalkyl orthosilicates emerged as highly effective reagents for the direct triple esterification of 85\u2009% phosphoric acid, as well as the esterification of organophosphinic and phosphonic acids. Furthermore, we achieved esterification of recovered phosphoric acid with tetraalkyl orthosilicate, thus pioneering a recycling pathway from sewage waste to valuable phosphorus chemicals. Experimental and theoretical investigations revealed a novel mechanism, wherein tetraalkyl orthosilicates facilitate multimolecular aggregation to achieve alkyl transfer from tetraalkylorthosilicate to phosphoric acid via multiple proton shuttling.<\/jats:p>","DOI":"10.1002\/anie.202416487","type":"journal-article","created":{"date-parts":[[2024,11,14]],"date-time":"2024-11-14T12:49:11Z","timestamp":1731588551000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["One\u2010Step Esterification of Phosphoric, Phosphonic and Phosphinic Acids with Organosilicates: Phosphorus Chemical Recycling of Sewage Waste"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3041-7638","authenticated-orcid":false,"given":"Yuki","family":"Naganawa","sequence":"first","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kei","family":"Sakamoto","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Akira","family":"Fujita","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kazuya","family":"Morimoto","sequence":"additional","affiliation":[{"name":"Research Institute for Geo-Resources and Environment National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8567 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manussada","family":"Ratanasak","sequence":"additional","affiliation":[{"name":"Institute for Catalysis Hokkaido University  Sapporo Hokkaido 001-0021 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9700-3309","authenticated-orcid":false,"given":"Jun\u2010ya","family":"Hasegawa","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"},{"name":"Institute for Catalysis Hokkaido University  Sapporo Hokkaido 001-0021 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masaru","family":"Yoshida","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kazuhiko","family":"Sato","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6813-8733","authenticated-orcid":false,"given":"Yumiko","family":"Nakajima","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"},{"name":"School of Materials and Chemical Technology Tokyo Institute of Technology  2-12-1 Ookayama Meguro-ku Tokyo 152-8552 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,4]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"Phosphorus Recovery and Recycling(Eds.: H. 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