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However, stability and selectivity under high current densities for practical application remain challenging. Herein, a CeF\n                    <jats:sub>3<\/jats:sub>\n                    @Ni\n                    <jats:sub>3<\/jats:sub>\n                    N nanosheets array anchored on carbon cloth (CeF\n                    <jats:sub>3<\/jats:sub>\n                    @Ni\n                    <jats:sub>3<\/jats:sub>\n                    N\/CC) was fabricated. The gradual extrusion of F species from Ni(OH)\n                    <jats:sub>2<\/jats:sub>\n                    lattices can stabilize hierarchical structure and construct abundant heterostructure interfaces. Moreover, CeF\n                    <jats:sub>3<\/jats:sub>\n                    can modulate electron distribution of Ni\n                    <jats:sub>3<\/jats:sub>\n                    N, thus simultaneously enhancing the surface adsorption kinetics and capability of methanol and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    , which is conducive to enhanced methanol oxidation reaction (MOR) activity and selectivity. Therefore, bifunctional CeF\n                    <jats:sub>3<\/jats:sub>\n                    @Ni\n                    <jats:sub>3<\/jats:sub>\n                    N\/CC exhibits low potential of 1.43\u2005V at 500\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , along with high stability over 72\u2005h and high faradaic efficiency (FEs) in MOR, as well as an overpotential of 76\u2005mV to achieve 50\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for hydrogen evolution reaction (HER). Furthermore, membrane\u2010free CeF\n                    <jats:sub>3<\/jats:sub>\n                    @Ni\n                    <jats:sub>3<\/jats:sub>\n                    N\/CC||CeF\n                    <jats:sub>3<\/jats:sub>\n                    @Ni\n                    <jats:sub>3<\/jats:sub>\n                    N\/CC cell for MOR||HER delivers high electrocatalytic activity, long\u2010term stability and FEs at high current density of 300\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This study highlights the importance of optimizing surface adsorption behavior of active species, as well as rational design of highly efficient heterostructure electrocatalysts for methanol upgrading coupled with hydrogen production.\n                  <\/jats:p>","DOI":"10.1002\/anie.202416763","type":"journal-article","created":{"date-parts":[[2024,11,10]],"date-time":"2024-11-10T23:49:02Z","timestamp":1731282542000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":56,"title":["Enhanced Adsorption Kinetics and Capacity of a Stable CeF\n                    <sub>3<\/sub>\n                    @Ni\n                    <sub>3<\/sub>\n                    N Heterostructure for Methanol Electro\u2010Reforming Coupled with Hydrogen Production"],"prefix":"10.1002","volume":"64","author":[{"given":"Kuan","family":"Deng","sequence":"first","affiliation":[{"name":"School of Chemical Engineering State Key Laboratory of Polymer Materials Engineering Sichuan University  Chengdu 610065 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuesong","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering State Key Laboratory of Polymer Materials Engineering Sichuan University  Chengdu 610065 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering State Key Laboratory of Polymer Materials Engineering Sichuan University  Chengdu 610065 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingbin","family":"Lv","sequence":"additional","affiliation":[{"name":"College of Chemistry and Environment Southwest Minzu University  Chengdu Sichuan 610041 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen","family":"Tian","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering State Key Laboratory of Polymer Materials Engineering Sichuan University  Chengdu 610065 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5545-1357","authenticated-orcid":false,"given":"Junyi","family":"Ji","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering State Key Laboratory of Polymer Materials Engineering Sichuan University  Chengdu 610065 P. R. 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