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While dimethyl sulfoxide (DMSO) is traditionally used to manage this process, its removal from the films is problematic. In this work, methyl phenyl sulfoxide (MPSO) was employed instead of DMSO to slow the crystallization rate, as MPSO is more easily removed from the perovskite structure. The electron delocalization associated with the benzene ring in MPSO decreases the electron density around the oxygen atom in the sulfoxide group, thus reducing its interaction with PbI\n                    <jats:sup>2<\/jats:sup>\n                    . This strategy not only sustains the formation of a crystallization\u2010slowing intermediate phase but also simplifies the elimination of the additive. Consequently, the optimized PSCs achieved a leading power conversion efficiency (PCE) of 25.95\u2009% along with exceptional stability. This strategy provides a novel method for fine\u2010tuning perovskite crystallization to enhance the overall performance of photovoltaic devices.\n                  <\/jats:p>","DOI":"10.1002\/anie.202416887","type":"journal-article","created":{"date-parts":[[2024,10,18]],"date-time":"2024-10-18T07:14:28Z","timestamp":1729235668000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["Removal of Residual Additive Enabling Perfect Crystallization of Photovoltaic Perovskites"],"prefix":"10.1002","volume":"64","author":[{"given":"Ze\u2010Kai","family":"Bian","sequence":"first","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials &amp; Devices Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhuang","family":"Su","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai 201204 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8708-8679","authenticated-orcid":false,"given":"Yan\u2010Hui","family":"Lou","sequence":"additional","affiliation":[{"name":"College of Energy Soochow Institute for Energy and Materials Innovations Soochow University  Suzhou 215006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; 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