{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T19:05:40Z","timestamp":1792177540858,"version":"4.4.0"},"reference-count":39,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2024,11,13]],"date-time":"2024-11-13T00:00:00Z","timestamp":1731456000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2024,11,13]],"date-time":"2024-11-13T00:00:00Z","timestamp":1731456000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100020931","name":"Central European Research Infrastructure Consortium","doi-asserted-by":"publisher","award":["20227190"],"award-info":[{"award-number":["20227190"]}],"id":[{"id":"10.13039\/100020931","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001823","name":"Ministerstvo \u0160kolstv\u00ed, Ml\u00e1de\u017ee a T\u011blov\u00fdchovy","doi-asserted-by":"publisher","award":["LM2023072"],"award-info":[{"award-number":["LM2023072"]}],"id":[{"id":"10.13039\/501100001823","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010890","name":"Chinese Government Scholarship","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100010890","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003246","name":"Nederlandse Organisatie voor Wetenschappelijk Onderzoek","doi-asserted-by":"publisher","award":["184.034.014"],"award-info":[{"award-number":["184.034.014"]}],"id":[{"id":"10.13039\/501100003246","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,1,21]]},"abstract":"Abstract<\/jats:title>\n \n ZnO\/ZrO\n 2<\/jats:sub>\n catalysts have shown better activity in the CO\n 2<\/jats:sub>\n hydrogenation to methanol compared with single component counterparts, but the interaction between ZnO and ZrO\n 2<\/jats:sub>\n is still poorly understood. In particular, the effect of the ZrO\n 2<\/jats:sub>\n support phase (tetragonal vs. monoclinic) was not systematically explored. Here, we have synthesized ZnO\/ZrO\n 2<\/jats:sub>\n catalysts supported on tetragonal ZrO\n 2<\/jats:sub>\n (ZnO\/ZrO\n 2<\/jats:sub>\n \u2010t) and monoclinic ZrO\n 2<\/jats:sub>\n (ZnO\/ZrO\n 2<\/jats:sub>\n \u2010m), which resulted in the formation of different ZnO\n x<\/jats:sub>\n species, consisting of sub\u2010nanometer ZnO moieties and large\u2010sized ZnO particles, respectively. ZnO\/ZrO\n 2<\/jats:sub>\n \u2010t exhibited a higher methanol selectivity (81 vs. 39\u2009%) and methanol yield (1.25 vs. 0.67\u2005mmol\u2009g\n \u22121<\/jats:sup>\n \u2009h\n \u22121<\/jats:sup>\n ) compared with ZnO\/ZrO\n 2<\/jats:sub>\n \u2010m. The difference in performance was attributed to the redox state and degree of dispersion of Zn, based on spectroscopy and microscopy results. ZnO\/ZrO\n 2<\/jats:sub>\n \u2010t had a high density of ZnO\n x<\/jats:sub>\n \u2010ZrO\n y<\/jats:sub>\n sites, which favored the formation of active HCOO* species and enhanced the yield and selectivity of methanol along the formate pathway. Such ZnO clusters were further dispersed on ZrO\n 2<\/jats:sub>\n \u2010t during catalysis, while larger ZnO particles on ZnO\/ZrO\n 2<\/jats:sub>\n \u2010m remained stable throughout the reaction. This study shows that the phase of ZrO\n 2<\/jats:sub>\n supports can be used to control the dispersion of ZnO and the catalyst surface chemistry, and lead to enhanced catalytic performance.\n <\/jats:p>","DOI":"10.1002\/anie.202416899","type":"journal-article","created":{"date-parts":[[2024,10,8]],"date-time":"2024-10-08T12:06:51Z","timestamp":1728389211000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Highly Dispersed ZnO Sites in a ZnO\/ZrO\n 2<\/sub>\n Catalyst Promote Carbon Dioxide\u2010to\u2010Methanol Conversion"],"prefix":"10.1002","volume":"64","author":[{"given":"Xibo","family":"Zhang","sequence":"first","affiliation":[{"name":"Inorganic Chemistry and Catalysis Group, Institute for Sustainable and Circular Chemistry Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands"},{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces & Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang","family":"Yu","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry and Catalysis Group, Institute for Sustainable and Circular Chemistry Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rafael G.","family":"Mendes","sequence":"additional","affiliation":[{"name":"Soft Condensed Matter Group, Debye Institute for Nanomaterials Science Utrecht University Heidelberglaan 8 3584 CS Utrecht The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Matvija","sequence":"additional","affiliation":[{"name":"Charles University, Faculty of Mathematics and Physics Department of Surface and Plasma Science V Hole\u0161ovi\u010dk\u00e1ch 2 Prague 18000 Praha 8 Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Angela E. M.","family":"Melcherts","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry and Catalysis Group, Institute for Sustainable and Circular Chemistry Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunning","family":"Sun","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry and Catalysis Group, Institute for Sustainable and Circular Chemistry Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinwei","family":"Ye","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry and Catalysis Group, Institute for Sustainable and Circular Chemistry Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bert M.","family":"Weckhuysen","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry and 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