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Herein, the pyrolysis\u2010free synthetic method is developed to integrate single atoms and nanoclusters towards highly satisfactory catalytic performances for both acidic and alkaline hydrogen electrocatalysis. The controllable pyrolysis\u2010free strategy allows the precise modulation of the active centers, realizing the optimization of the adsorption energy and the regulation of the synergistic active components. Specially, the as\u2010prepared catalysts with hybrid single\u2010atom\/nanocluster sites exhibited superior catalytic activities for hydrogen evolution in both acidic and alkaline media with low over\u2010potentials at \u221210\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    of 25\u2005mV and 8.6\u2005mV, respectively, combining with outstanding durability towards high current density and methanol poisoning. This work developed a universal synthetic strategy for the single atom\/nanocluster synergy systems and addressed the superiority of hybrid single\u2010atom\/nanocluster sites.\n                  <\/jats:p>","DOI":"10.1002\/anie.202416973","type":"journal-article","created":{"date-parts":[[2024,11,6]],"date-time":"2024-11-06T07:49:39Z","timestamp":1730879379000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Pyrolysis\u2010Free Synthesis of Synergistic Single\u2010Atom\/Nanocluster Electrocatalysts for Hydrogen Evolution"],"prefix":"10.1002","volume":"64","author":[{"given":"Zhao\u2010Di","family":"Wang","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials and College of Chemistry Zhengzhou University  Zhengzhou 450001 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