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In this study, we present a facile and benign electrochemical pathway for synthesis of glycine through reductive coupling of glyoxylic acid and nitrate over a copper\u2010bismuth bimetal catalyst derived from a metal\u2013organic framework (MOF) array on copper foam (Cu\/Bi\u2212C@CF). Remarkably, Cu\/Bi\u2212C@CF achieves a fantastic selectivity of 89\u2009%, corresponding a high Faraday efficiency of 65.9\u2009%. From control experiments, the introduction of Bi caused the binding energy of Cu shift to a lower state, which leads to a high selectivity towards the formation of key intermediate hydroxylamine rather than ammonia product, facilitating the formation of oxime and providing additional sites for subsequent hydrogenation reaction on the way to glycine. Moreover, the derivation of MOF arrays ensures the effective dispersion of Bi and enhances the stability of Cu\/Bi\u2212C@CF. This innovative approach not only presents sustainable pathways for the production of value\u2010added organonitrogen compounds utilizing readily available carbon and nitrogen sources, but also provides novel insights into the design of multistage structural catalysts for sequential reactions.<\/jats:p>","DOI":"10.1002\/anie.202417130","type":"journal-article","created":{"date-parts":[[2024,9,29]],"date-time":"2024-09-29T23:54:46Z","timestamp":1727654086000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":98,"title":["Cu\u2212Bi Bimetallic Catalysts Derived from Metal\u2013Organic Framework Arrays on Copper Foam for Efficient Glycine Electrosynthesis"],"prefix":"10.1002","volume":"64","author":[{"given":"Peisen","family":"Liao","sequence":"first","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binning","family":"Zeng","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suisheng","family":"Li","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhao","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei 230029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Runan","family":"Xiang","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiawei","family":"Kang","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qinghua","family":"Liu","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei 230029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1233-5591","authenticated-orcid":false,"given":"Guangqin","family":"Li","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,9]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1177\/0148607198022006393"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00726-013-1493-1"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nrc3557"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-14387-8_5"},{"key":"e_1_2_7_6_1","first-page":"35","volume":"49","author":"Zhao J.","year":"2024","journal-title":"Low-Carbon Chem. 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