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Nevertheless, the instability of electrolyte\/electrode interface film and commercial electrolytes with cut\u2010off voltage above 4.3\u2005V is still a major concern. Herein, we present that excellent cycling stability with an ultra\u2010high cut\u2010off voltage of up to 5.0\u2005V can be obtained by using three\u2010component additives containing fluoroethylene carbonate (FEC), hexadecyl trimethylammonium chloride (CTAC), and tri(pentafluorophenyl)borane (TPFPB). Excellent ionic conductivity, robust interfacial films on both electrodes, and long\u2010lasting uniform Li\n                    <jats:sup>+<\/jats:sup>\n                    regulation ability can be obtained in the modifying electrolyte. Consequently, using a high plating\/stripping capacity of 3\u2005mAh\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    under the current density of 1\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , lithium symmetric cells demonstrate stable cycling performance exceeding 800\u2005hours. Meanwhile, the 7.3\u2005Ah\u2010class Li[Ni\n                    <jats:sub>x<\/jats:sub>\n                    Co\n                    <jats:sub>y<\/jats:sub>\n                    Mn\n                    <jats:sub>1\u2010x\u2010y<\/jats:sub>\n                    ]O\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>x<\/jats:italic>\n                    =0.83, NCM83)|Li pouch cells are assembled, which show a high energy density of 522\u2005Wh\u2009kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    and present excellent stability over 178\u2005cycles with a high initial coulombic efficiency (CE) of 98.0\u2009%.\n                  <\/jats:p>","DOI":"10.1002\/anie.202417471","type":"journal-article","created":{"date-parts":[[2024,10,8]],"date-time":"2024-10-08T12:41:39Z","timestamp":1728391299000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Long\u2010Lifespan 522\u2005Wh\u2009kg\n                    <sup>\u22121<\/sup>\n                    Lithium Metal Pouch Cell Enabled by Compound Additives Engineering"],"prefix":"10.1002","volume":"64","author":[{"given":"Tingxuan","family":"Tang","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science Jiangsu Normal University  Xuzhou, Jiangsu 201116 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-8760-2757","authenticated-orcid":false,"given":"Chuang","family":"Sun","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 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