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Compound <jats:bold>2<\/jats:bold> was synthesized via phenylsilane metathesis with the corresponding amide (<jats:sup>dtbp<\/jats:sup>Cbz)SrN(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> and characterized by <jats:sup>1<\/jats:sup>H NMR, XRD and vibrational spectroscopy methods. We further investigated the stoichiometric reactivity of <jats:bold>2<\/jats:bold> towards carbon monoxide, azobenzene and trimethylsilylacetylene, showing three distinct reactivity pathways: addition, reduction and deprotonation. The reaction of <jats:bold>2<\/jats:bold> with carbon monoxide yields the ethenediolate complex <jats:bold>4<\/jats:bold> via addition, while with azobenzene reduction of the N\u2212N double bond and release of hydrogen were observed, affording a heteroleptic strontium complex with a radical azobenzenyl ligand (<jats:bold>5<\/jats:bold>). The terminal alkyne is deprotonated by the hydride moiety to give the acetylide complex <jats:bold>6<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/anie.202418558","type":"journal-article","created":{"date-parts":[[2024,11,29]],"date-time":"2024-11-29T05:33:50Z","timestamp":1732858430000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Stabilisation of a Strontium Hydride with a Monodentate Carbazolyl Ligand and its Reactivity"],"prefix":"10.1002","volume":"64","author":[{"given":"Lucas","family":"Winkler","sequence":"first","affiliation":[{"name":"Karlsruhe Institute of Technology (KIT) Institute of Inorganic Chemistry (AOC)  Engesserstr. 15, Geb. 30.45 Karlsruhe Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7831-1410","authenticated-orcid":false,"given":"Alexander","family":"Hinz","sequence":"additional","affiliation":[{"name":"Karlsruhe Institute of Technology (KIT) Institute of Inorganic Chemistry (AOC)  Engesserstr. 15, Geb. 30.45 Karlsruhe Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,12,10]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/b110117j"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200601013"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200701028"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc33478j"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00880H"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00743"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0006-0"},{"key":"e_1_2_3_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00097H"},{"key":"e_1_2_3_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201708592"},{"key":"e_1_2_3_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801869"},{"key":"e_1_2_3_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706786"},{"key":"e_1_2_3_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC04330C"},{"key":"e_1_2_3_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC09362D"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b13796"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901548"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201814733"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC02040D"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c03894"},{"key":"e_1_2_3_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201810026"},{"key":"e_1_2_3_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200701255"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201904148"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00278"},{"key":"e_1_2_3_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709344"},{"journal-title":"Chem. 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