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Hitherto, low\u2010energy and mild\u2010condition PRMW remains a serious challenge. Here, the amino acid\u2010derived carbon nitrides (ACN) were synthesized supramolecular precursor strategy for PRMW and achieved excellent performance (H\n                    <jats:sub>2<\/jats:sub>\n                    , 35.6\u2005mmol\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ; CO\n                    <jats:sub>2<\/jats:sub>\n                    , 11.5\u2005mmol\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) under sunlight at 35\u2009\u00b0C. It was revealed that the surface\u2010terminating carboxyl groups (\u2212COOH) promote the dark dehydrogenation of methanol on MetCN\n                    <jats:italic>x<\/jats:italic>\n                    to form methoxy (*OCH\n                    <jats:sub>3<\/jats:sub>\n                    ) and methylol (*CH\n                    <jats:sub>2<\/jats:sub>\n                    OH) simultaneously, with the hydroxyl (*OH) generated by photostimulated H\n                    <jats:sub>2<\/jats:sub>\n                    O oxidation promotes the C\u2212H activation of formaldehyde, then leads the whole reaction into the formation of CO\n                    <jats:sub>2<\/jats:sub>\n                    and three H\n                    <jats:sub>2<\/jats:sub>\n                    . The extended light absorption, enhanced charge separation and transport, and efficient surface reaction improve photocatalytic efficiency.\n                  <\/jats:p>","DOI":"10.1002\/anie.202418677","type":"journal-article","created":{"date-parts":[[2024,10,31]],"date-time":"2024-10-31T23:15:39Z","timestamp":1730416539000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Mild\u2010Condition Photocatalytic Reforming of Methanol\u2010Water by a Hierarchical, Asymmetry Carbon Nitride"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5773-6209","authenticated-orcid":false,"given":"Baogang","family":"Wu","sequence":"first","affiliation":[{"name":"Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education of the People's Republic of China School of Chemistry and Materials Science Heilongjiang University  150080 Harbin P.\u2005R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiawei","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education of the People's Republic of China School of Chemistry and Materials Science Heilongjiang University  150080 Harbin P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Li","sequence":"additional","affiliation":[{"name":"College of Material Science and Chemical Engineering Harbin Engineering University  150001 Harbin P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education of the People's Republic of China School of Chemistry and Materials Science Heilongjiang University  150080 Harbin P.\u2005R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8395-7558","authenticated-orcid":false,"given":"Markus","family":"Antonietti","sequence":"additional","affiliation":[{"name":"Department of Colloid Chemistry Max Planck Institute of Colloids and Interfaces  14476 Potsdam Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5800-451X","authenticated-orcid":false,"given":"Honggang","family":"Fu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education of the People's Republic of China School of Chemistry and Materials Science Heilongjiang University  150080 Harbin P.\u2005R. 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