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Formally, H<jats:sub>3<\/jats:sub>COH is added to the C=C bond in a 100\u2009% atom efficient manner. Mechanistically, the overall transformation occurs as a tandem reaction sequence by combining the dehydrogenation of methanol to syngas at a CO\u2009:\u2009H<jats:sub>2<\/jats:sub> ratio of 1\u2009:\u20092 with subsequent hydroformylation to the corresponding aldehyde and its final hydrogenation to the alcohol. The dehydrogenation and hydrogenation steps are catalyzed by a Mn\/pincer complex, while the hydroformylation is accomplished by a Rh\/phosphine catalyst. Using 1\u2010octene as prototypical substrate, a yield of 80\u2009% nonanol was achieved with a ratio of 93\u2009:\u20097 of linear to branched alcohols and turnover numbers (TON<jats:sub>Rh<\/jats:sub>) of more than 17 000 could be obtained in relation to the precious metal Rhodium. The integrated catalytic system provides direct access to alcohols from olefins and \u201cgreen\u201d methanol, avoiding the handling of pressurized CO and H<jats:sub>2<\/jats:sub> and the use of specialized high\u2010pressure equipment as the process conditions do not exceed 10\u2005bar with partial pressures of syngas in the range of only 1\u20132\u2005bar.<\/jats:p>","DOI":"10.1002\/anie.202418984","type":"journal-article","created":{"date-parts":[[2024,11,19]],"date-time":"2024-11-19T06:04:48Z","timestamp":1731996288000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Methanolation of Olefins: Low\u2010Pressure Synthesis of Alcohols by the Formal Addition of Methanol to Olefins"],"prefix":"10.1002","volume":"64","author":[{"given":"Sebastian","family":"Stahl","sequence":"first","affiliation":[{"name":"Max Planck Institute for Chemical Energy Conversion  Stiftstra\u00dfe 34\u201336 45470 M\u00fclheim an der Ruhr Germany"},{"name":"Institute for Technical and Macromolecular Chemistry RWTH Aachen University  Worringerweg 2 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeroen T.","family":"Vossen","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Chemical Energy Conversion  Stiftstra\u00dfe 34\u201336 45470 M\u00fclheim an der Ruhr Germany"},{"name":"Institute for Technical and Macromolecular Chemistry RWTH Aachen University  Worringerweg 2 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephan","family":"Popp","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Chemical Energy Conversion  Stiftstra\u00dfe 34\u201336 45470 M\u00fclheim an der Ruhr Germany"},{"name":"Institute for Technical and Macromolecular Chemistry RWTH Aachen University  Worringerweg 2 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8747-0723","authenticated-orcid":false,"given":"Walter","family":"Leitner","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Chemical Energy Conversion  Stiftstra\u00dfe 34\u201336 45470 M\u00fclheim an der Ruhr Germany"},{"name":"Institute for Technical and Macromolecular Chemistry RWTH Aachen University  Worringerweg 2 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9302-2273","authenticated-orcid":false,"given":"Andreas J.","family":"Vorholt","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Chemical Energy Conversion  Stiftstra\u00dfe 34\u201336 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,4]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE01673B"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-39709-7"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527805662"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202007397"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00435"},{"key":"e_1_2_8_6_1","first-page":"551","volume":"25","author":"Sonthalia A.","year":"2023","journal-title":"Clean Technol. 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