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However, there remains a significant challenge for the synthesis of methanol by using O<jats:sub>2<\/jats:sub> at low temperature. Inspired by the catalytic structure in soluble methane monooxygenase (MMO) and the corresponding reaction mechanism, we prepared a biomimetic photocatalyst with the decoration of Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanoclusters and satellite Fe single atoms immobilized on carbon nitride. The catalyst demonstrates an excellent CH<jats:sub>3<\/jats:sub>OH productivity of 5.02\u2005mmol\u2009\u22c5\u2009g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup>\u2009\u22c5\u2009h<jats:sup>\u22121<\/jats:sup> with CH<jats:sub>3<\/jats:sub>OH selectivity of 98.5\u2009%. Mechanism studies reveal that the synergy between Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanoclusters and Fe single atoms establishes a dual\u2010Fe site as MMO for O<jats:sub>2<\/jats:sub> activation and subsequent CH<jats:sub>4<\/jats:sub> partial oxidation. Moreover, the light excitation of Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanoclusters with a relative narrow band gap could deliver the electrons and protons to atomic Fe that facilitating the oxygen reduction kinetics for the robust of CH<jats:sub>3<\/jats:sub>OH synthesis.<\/jats:p>","DOI":"10.1002\/anie.202419075","type":"journal-article","created":{"date-parts":[[2024,10,10]],"date-time":"2024-10-10T12:19:38Z","timestamp":1728562778000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Iron Oxide Clusters as Electron Donors Under Light Enhance Oxygen Reduction Kinetics at Atomically Dispersed Fe for Photocatalytic CH<sub>4<\/sub> Partial Oxidation"],"prefix":"10.1002","volume":"64","author":[{"given":"Yueyuan","family":"Xu","sequence":"first","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianfeng","family":"Shen","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuai","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences  Taiyuan Shanxi 030001 P.R. 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